
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:9. For the DNA segment with nucleotide sequence 5' TATCGC 3’, how many hydrogen
bonds in total hold the base pairs between this segment and its complementary strand?
А. 5
В.
6
С. 15
D. 18
E. Cannot be determined
10. What is the relation between the Fischer projection of two molecules below?
H
H-
-OH
Но-
но-
H-
Но
H-
H-
-OH-
Но-
CH2OH
CH2OH
A. C2 epimers
В. СЗ ерimers
C. Enantiomers
D. Anomers
E. Superimposable molecules
Section B: True / False (10 marks)
A group is deprotonated when its pKa value is lower than the pH of
the solution.
1.
T or F
2.
a and B configurations are used to describe enantiomers.
T or F
3.
Hydrogen bond can be formed between two peptide bonds.
T or F
4.
A single strand of RNA has 20% U so it also has 20% A.
T or F
5.
Arginine's pI lies between 2.34 and 9.6.
T or F
6.
O-6 fatty acids have fewer double bonds than @-9 fatty acids have.
T or F
7.
The net charge of glycine changes at different pH.
T or F
8.
The hydroxyl group in threonine is deprotonated at high pH.
T or F
9.
Deoxyguanosine contains a monophosphate.
T or F
10. Ketohexose gives positive result in Benedict's test.
T or F
3

Transcribed Image Text:Section C: Short Questions
1. Consider the peptide with amino acid sequence NICE.
а.
Write the full name and the three-letter abbreviations of the amino acids in the
(8 marks)
Calculate the net charge of the peptide at pH 7.0. Show you work in a table. Step
(3 marks)
Calculate the pI of the peptide. Show you work in a table. Step marks are counted.
(6 marks)
peptide.
b.
marks are counted.
с.
2. Write the full name of amino acids, from N-terminus to C-terminus, after hydrolysis of
the following polypeptide. How many peptide bonds are present?
(5 marks)
H,N-CH-C-
CH-
CH-C
N-CH-C-0-
H,C-CH
H CH,
CH2
H ČH,-C-NH,
ČH
H
3. Complete the following table. (9 marks; 0.5 mark @ for a-d, 1 mark @ for e)
а.
СНО
b.
CH,OH
СНО
с.
HO-H
HO
-H-
C=0
H-
-OH
H-
-O-
H
-O-
HO-H
HO-*H
Нон
CH,OH
HO-H
HO-*H
CH,OH
CH-OH
a. Number of
chiral carbon
b. D or L
configuration
c. Aldose or
ketose?
d. If the -OH of
carbon with *
forms a bond
with the carbon
of the carbonyl
group, the cyclic
form will be a
furanose or
pyranose?
4
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