8.45 As we've seen, alkynes undergo many of the same addition reactions that alkenes do. What product might you expect from each of the fol- lowing reactions? 1 equiv Brz. ? CH3 (a) CH3CHCH2CH2C=CH 2 equiv H2, Pd/C (b) (c) 1 equiv HBr CH3 - CH3 (a) (b) CH3 CH3CHCH2CH2CH2CH3 ? Hy/Pd ? HyPd (c) Br CH3 (d) Br2. HCI CH3CHCHCH,CHCH3 CH3CHCHCH2CH2CH2CH3 CH3 Br (e) он 1. Hg(OAc)2, H20 2. NABH4 CH3CH2CH2CHCH3

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.46P
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8.45 As we've seen, alkynes undergo many of the same addition reactions
that alkenes do. What product might you expect from each of the fol-
lowing reactions?
1 equiv Br2
CH3
(a)
CH3CHCH2CH2C=CH
2 equiv H2, Pd/C
(b)
(c)
1 equiv HBr
CH3
- CH3
(a)
(b)
CH3
CH3CHCH2CH2CH2CH3
? H2/Pd
? HyPd
(c)
Br
CH3
(d)
? HCI
CH3CHCHCH2CH2CH2CH3
Br2
CH3CHCHCH2CHCH3
Br
CH3
(e)
он
1. Hg(OAc)2, H20
2. NaBH4
CH3CH2CH2CHCH3
Transcribed Image Text:8.45 As we've seen, alkynes undergo many of the same addition reactions that alkenes do. What product might you expect from each of the fol- lowing reactions? 1 equiv Br2 CH3 (a) CH3CHCH2CH2C=CH 2 equiv H2, Pd/C (b) (c) 1 equiv HBr CH3 - CH3 (a) (b) CH3 CH3CHCH2CH2CH2CH3 ? H2/Pd ? HyPd (c) Br CH3 (d) ? HCI CH3CHCHCH2CH2CH2CH3 Br2 CH3CHCHCH2CHCH3 Br CH3 (e) он 1. Hg(OAc)2, H20 2. NaBH4 CH3CH2CH2CHCH3
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