Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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please do question 1, all parts of it!

**Exercise 8.30**

**Objective:** Draw the complete, detailed mechanism, including curved arrows, for each of the following reactions occurring via (a) an S<sub>N</sub>2 mechanism and (b) an S<sub>N</sub>1 mechanism. Pay attention to stereochemistry.

---

**(i)** 

**Reactants:** A cyclohexane ring with a bromine (Br) substituent.

- **Reagents:** NaOH

- **Reaction:** ?

---

**(ii)** 

**Reactants:** A cyclohexane ring with an iodine (I) substituent, showing a wedge bond indicating stereochemistry. There is also a methyl (CH<sub>3</sub>) group on the cyclohexane in the back.

- **Reagents:** NaOH 

- **Reaction:** ?

---

**(iii)** 

**Reactants:** A cyclohexane ring with an iodine (I) substituent, depicted with a dashed bond, indicating stereochemistry. Also includes a methyl (CH<sub>3</sub>) group in the front.

- **Reagents:** NaOH

- **Reaction:** ?

---

**(iv)** 

**Reactants:** A cyclohexane ring with an iodine (I) and a methyl (CH<sub>3</sub>) substituent, both depicted with wedge bonds, indicating stereochemistry.

- **Reagents:** KBr

- **Reaction:** ?

---

**Page Reference:** Problems / 457

**Instructions:** Consider the stereochemistry when proposing mechanism pathways.
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Transcribed Image Text:**Exercise 8.30** **Objective:** Draw the complete, detailed mechanism, including curved arrows, for each of the following reactions occurring via (a) an S<sub>N</sub>2 mechanism and (b) an S<sub>N</sub>1 mechanism. Pay attention to stereochemistry. --- **(i)** **Reactants:** A cyclohexane ring with a bromine (Br) substituent. - **Reagents:** NaOH - **Reaction:** ? --- **(ii)** **Reactants:** A cyclohexane ring with an iodine (I) substituent, showing a wedge bond indicating stereochemistry. There is also a methyl (CH<sub>3</sub>) group on the cyclohexane in the back. - **Reagents:** NaOH - **Reaction:** ? --- **(iii)** **Reactants:** A cyclohexane ring with an iodine (I) substituent, depicted with a dashed bond, indicating stereochemistry. Also includes a methyl (CH<sub>3</sub>) group in the front. - **Reagents:** NaOH - **Reaction:** ? --- **(iv)** **Reactants:** A cyclohexane ring with an iodine (I) and a methyl (CH<sub>3</sub>) substituent, both depicted with wedge bonds, indicating stereochemistry. - **Reagents:** KBr - **Reaction:** ? --- **Page Reference:** Problems / 457 **Instructions:** Consider the stereochemistry when proposing mechanism pathways.
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