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- 16.41 Draw the products of each reaction. a. b. HO NO₂ mellanrios H HNO3 H₂SO4 Br₂ FeBr3 AICI3 d. e. Br- edmun adtonie F prier f. F (X) napoln NO₂ Cl₂ FeCl3 SO3 H₂SO4 onho sur + Na S9.61. Which reagent (or reagents) will achieve the following transformation? Br ? a. Br₂ b. Br₂, H₂O c. xs HBr, ROOR d. xs HBr Br16.41 Draw the products of each reaction. а. HNO3 H2SO4 'NO2 HO b. AICI3 CI С. H. Br2 FeBr3
- Choose the most correct set of reagents for the following reactions. 1.? OMe 2. ? a. 1. MsCI, pyridine; 2. NaOH, H2O2, H2O b. 1. HCI, pyridine NaOCH3, CH;OH c. 1. Pl3, pyridine; 2. NaOCH3, CH;OH d. 1. TSCI, pyridine; 2. NaOCH3, CH3OH e. 1. CH30", pyridine; 2. H* f. 1. PBr3, pyridine; 2. H*8.45 Which of the following compounds undergoes E2 elimination with strong base? For compounds that undergo elimination, draw the product. For compounds that do not undergo elimination, explain why they are unreactive. а. Br b. Br с. Br H.9.60 Draw the products of each reaction. a. CH3CH2OH H₂SO4 b. ن C. d. [1] CH3CH₂O- Na+ Ο [2] H₂O HBr [1] NaCN [2] H₂O
- d. 8.65 Explain why each of the following alcohols cannot be prepared via hydroboration-oxidation: ОН 3. b. OH OHPredict the product for the following reaction: 1. 1 equivalent LDA, -78 °C ?? 2. CH;CH,Br8.54 س Draw a stepwise, detailed mechanism for the following reaction. H H Br H2O H OH + H H .OH + H ۲۰۰ + HBr
- 16.5 Predict the major product(s) of the reactions. NO₂ CI AICI 3Choose the best reagent(s) for carrying out the following reaction: A B 1. PhMgBr 2. H3O+ (D) C) NaBH4 Br. 1. CH3CH₂CH₂CH₂CH₂CH₂MgBr 2. H3O+ 1. CH3CH₂CH₂CH₂MgBr 2. H3O+ O Br OH :7. What is the major product? NaOH c. ? a. b. d. e. not a.-d.