7.37 Which product (or products) would you expect to obtain from each of the following reactions? In each part give the mechanism (SN1, SN2, E1, or E2) by which each product is formed and predict the relative amount of each product (i.e., would the product be the only product, the major product, a minor product, etc.?). Br EtO Meo (a) ELOH, 50 °C (g) 3-Chloropentane МеОН, 50 °С Br t-BUOK CH;CO2 (b) t-BUOH, 50 °C (h) 3-Chloropentane CHCO2Н, 50 °с Meo (c) HO Br МеОН, 50 °C (i) (R)-2-bromobutane 25 °C (d) t-BUOK 25 °C t-BUOH, 50 °C Br (j) (S)-3-Bromo-3-methylhexane MeOH (k) (S)-2-Bromooctane (e) t-Bu. МеОн, 50 °С acetone, 50 °C (1) (f) + NEC+ X→ Br + Br+ t-Bu, CN МеОН, 25 °С
7.37 Which product (or products) would you expect to obtain from each of the following reactions? In each part give the mechanism (SN1, SN2, E1, or E2) by which each product is formed and predict the relative amount of each product (i.e., would the product be the only product, the major product, a minor product, etc.?). Br EtO Meo (a) ELOH, 50 °C (g) 3-Chloropentane МеОН, 50 °С Br t-BUOK CH;CO2 (b) t-BUOH, 50 °C (h) 3-Chloropentane CHCO2Н, 50 °с Meo (c) HO Br МеОН, 50 °C (i) (R)-2-bromobutane 25 °C (d) t-BUOK 25 °C t-BUOH, 50 °C Br (j) (S)-3-Bromo-3-methylhexane MeOH (k) (S)-2-Bromooctane (e) t-Bu. МеОн, 50 °С acetone, 50 °C (1) (f) + NEC+ X→ Br + Br+ t-Bu, CN МеОН, 25 °С
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
Question
only e f g
Transcribed Image Text:7.37 Which product (or products) would you expect to obtain from each of the following reactions? In each part give the mechanism
(SN1, SN2, E1, or E2) by which each product is formed and predict the relative amount of each product (i.e., would the product be the
only product, the major product, a minor product, etc.?).
EtO
Br
ELOH, 50 °C
Meo
(a)
(g) 3-Chloropentane
МеОН, 50 °С
t-BUOK
Br
t-BUOH, 50 °C
CH;CO,
(b)
(h) 3-Chloropentane
CHCO2Н, 50 °С
Meo
(c)
Но
Br
МеОН, 50 °C
(i) (R)-2-bromobutane
25 °C
t-BUOK
25 °C
(d)
t-BUOH, 50 °C
Br
(j) (S)-3-Bromo-3-methylhexane
MeOH
(k) (S)-2-Bromooctane
(e)
t-Bu
МеОН, 50 °C
acetone, 50 °C
ÇI
(1)
+ Br+
(f)
+ NEC+ -X→
Br
t-Bu.
CN
МеОН, 25 °C
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