Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Organic Chemistry 1

Here is the professor's solution to the problem. However, I do NOT understand the solution. Please explain the answer in a clear step-by-step fashion to me. Explain the answer provided in the image in a clear fashion and as if I did not know much about organic chemistry. It seems to me like the professor is making the problem more complicated than it has to be. Can you demystify or simplify this problem about D glucose?

How can you assign priorities on a Fischer projection? I don't get it.

 

7. D-glucose, blood sugar, exists in two forms; ring open and ring closed. Don't worry
about the chemistry of ring closure (but FYI, arrows are pointing at the atoms involved in
this cyclization). This is an example of a problem that has all kinds of irrelevant
information that you have to ignore as you search for the actual questionO. Consider the
ring open form of D-Glucose What is the absolute configuration at C-3? How many
stereoisomers does the ring open form of D-glucose have? Using Fischer projections,
draw its enantiomer and on diastereomerlow many stereoisomers does the ring closed
form shown below have?
King open form
has'y'stereocenters
# stereo1s omers =
King Closed form has s
steieo centers: n=5
: # steveo1s omerj = 2°: 32
СНО
extract
C-3
C-3 H-
-ОН
posable
Stereoisomans
= 16
НО
HOH2C
Using Ch 17
Chemistry
НО
H.
-HO
НО_
HO
OH
3.
4+
of
expand button
Transcribed Image Text:7. D-glucose, blood sugar, exists in two forms; ring open and ring closed. Don't worry about the chemistry of ring closure (but FYI, arrows are pointing at the atoms involved in this cyclization). This is an example of a problem that has all kinds of irrelevant information that you have to ignore as you search for the actual questionO. Consider the ring open form of D-Glucose What is the absolute configuration at C-3? How many stereoisomers does the ring open form of D-glucose have? Using Fischer projections, draw its enantiomer and on diastereomerlow many stereoisomers does the ring closed form shown below have? King open form has'y'stereocenters # stereo1s omers = King Closed form has s steieo centers: n=5 : # steveo1s omerj = 2°: 32 СНО extract C-3 C-3 H- -ОН posable Stereoisomans = 16 НО HOH2C Using Ch 17 Chemistry НО H. -HO НО_ HO OH 3. 4+ of
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