Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- (a) Consider the mass transfer-limited reaction: A → 2B DAB = 0.01 cm²s-1 What would your concentration (mole fraction) profile look like as a function of distance (i.e. z/8)? What is the flux of A?arrow_forwardStart with the general mass balance relationship In – Out + Rxn = Accum and derive a formula that allows you to calculate the value of the first order reaction rate constant, k, given the half-life of a compound. Use the equation to determine the value of k for carbon tetrachloride (CCl4) given that CCl4 has a half-life of 8,030 days in air.arrow_forwardProblem IX (10 p): Consider the isomerization of compound A from its cis to its trans isomer at 298 K, which is first order in both directions: ki cis-A = trans-A k2 The rate constant for the forward reaction is k1 = 4.2 × 10* s', and the rate constant for the reverse reaction is k2 = 2.1 × 10-ª s-1. %3D a) Calculate the equilibrium concentrations [cis-A]eq and [trans-A]eq, assuming that at time t= 0 all of A was in the cis-form, i.e., [cis-A]o = [A]o. (Hint: Use the fact that at any time, [cis-A] + [trans-A] = [A]o.) %3D b) Which reaction is spontaneous, the forward reaction or the reverse reaction? Provide your reasoning. Total /100 parrow_forward
- The rate of a certain reaction is given by the following rate law: rate =kNO2O2 Use this information to answer the questions below. What is the reaction order in NO? What is the reaction order in O2? What is overall reaction order? At a certain concentration of NO and O2, the initial rate of reaction is 5.0 x 104 M / s. What would the initial rate of the reaction be if the concentration of NO were doubled? Be sure your answer has the correct number of significant digits. Ms The rate of the reaction is measured to be 40.0 M / s when [NO] = 0.57 M and [O2] = 2.0 M. Calculate the value of the rate constant. Be sure your answer has the correct number of significant digits. =k⋅M−2s−1arrow_forwardA chemical company performs the following synthetic reaction: 2 C19H16O - >C38H32O2 This reaction follows second-order kinetics with a rate constant of 4.1 L mole-1 min-1.If the reaction solution initially contains 0.050 M concentration of C19H16O, how much time is required for 95% of the C19H16O to react?arrow_forward
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