Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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### Problem 6: Titration of HCl with NaOH

**Task:** Calculate the pH of a solution during a titration of 2.5M HCl with 35mL of 1.25M NaOH.

#### Part A: 12mL of HCl

#### Part B: 30mL of HCl

#### Part C: Equivalence Point
How many mL of HCl are needed to reach the equivalence point?

---

To solve these problems, one needs to understand the principles of acid-base titration and the concept of equivalence point—where moles of acid equal moles of base. The pH at different stages of titration can be determined using stoichiometry and the properties of the substances involved.

#### Steps to Solve:
1. **Determine the moles of NaOH and HCl used**:
   - Moles of NaOH = Volume (L) × Molarity (M)
   - Moles of HCl = Volume (L) × Molarity (M)

2. **Calculate the point at which equivalence is reached** (Acid moles = Base moles).

3. **For Part A & B**:
   - Determine the remaining moles of acid/base after neutralization.
   - Calculate the concentration of H+ or OH- ions.
   - Use the concentration to find the pH or pOH (and convert as necessary to find pH if needed).

4. **For Part C**:
   - Set the moles of NaOH equal to the moles of HCl and solve for the volume of HCl.

---

This method will ensure a comprehensive understanding of titration calculations and the specific points along the titration curve.
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Transcribed Image Text:### Problem 6: Titration of HCl with NaOH **Task:** Calculate the pH of a solution during a titration of 2.5M HCl with 35mL of 1.25M NaOH. #### Part A: 12mL of HCl #### Part B: 30mL of HCl #### Part C: Equivalence Point How many mL of HCl are needed to reach the equivalence point? --- To solve these problems, one needs to understand the principles of acid-base titration and the concept of equivalence point—where moles of acid equal moles of base. The pH at different stages of titration can be determined using stoichiometry and the properties of the substances involved. #### Steps to Solve: 1. **Determine the moles of NaOH and HCl used**: - Moles of NaOH = Volume (L) × Molarity (M) - Moles of HCl = Volume (L) × Molarity (M) 2. **Calculate the point at which equivalence is reached** (Acid moles = Base moles). 3. **For Part A & B**: - Determine the remaining moles of acid/base after neutralization. - Calculate the concentration of H+ or OH- ions. - Use the concentration to find the pH or pOH (and convert as necessary to find pH if needed). 4. **For Part C**: - Set the moles of NaOH equal to the moles of HCl and solve for the volume of HCl. --- This method will ensure a comprehensive understanding of titration calculations and the specific points along the titration curve.
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