Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
Bartleby Related Questions Icon

Related questions

Question
**Example Problem: Analysis of NMR Spectrum**

**Chemical Data:**
- **Chemical Formula:** C₅H₁₀O₂
- **IR Spectrum:** Strong peak at 1750 cm⁻¹

**NMR Spectrum Analysis:**

The NMR spectrum presented shows three distinct signals with the following characteristics:

1. **Signal at ~5.0 ppm:**
   - Integration: 1H
   - This peak may correspond to a hydrogen atom in a deshielded environment, possibly near an electronegative atom or group.

2. **Signal at ~2.0 ppm:**
   - Integration: 3H
   - This peak suggests a methyl group (CH₃) possibly adjacent to a carbonyl or other electron-withdrawing group.

3. **Signal at ~1.0 ppm:**
   - Integration: 6H
   - This peak likely represents two equivalent methyl groups, possibly in an alkyl chain or equivalent environment.

**Note:**
The strong IR peak at 1750 cm⁻¹ indicates the presence of a carbonyl group, likely an ester or ketone, which influences the chemical environment of the hydrogen atoms in the molecule.

**Calculation Check:**
- The handwritten note "5×2 = 10 - 10 = 0" suggests a verification of the number of hydrogens in the chemical formula, confirming the spectrum accounts for all hydrogen atoms present.

This analysis can assist in identifying the structure of the compound C₅H₁₀O₂ by combining the NMR and IR data.
expand button
Transcribed Image Text:**Example Problem: Analysis of NMR Spectrum** **Chemical Data:** - **Chemical Formula:** C₅H₁₀O₂ - **IR Spectrum:** Strong peak at 1750 cm⁻¹ **NMR Spectrum Analysis:** The NMR spectrum presented shows three distinct signals with the following characteristics: 1. **Signal at ~5.0 ppm:** - Integration: 1H - This peak may correspond to a hydrogen atom in a deshielded environment, possibly near an electronegative atom or group. 2. **Signal at ~2.0 ppm:** - Integration: 3H - This peak suggests a methyl group (CH₃) possibly adjacent to a carbonyl or other electron-withdrawing group. 3. **Signal at ~1.0 ppm:** - Integration: 6H - This peak likely represents two equivalent methyl groups, possibly in an alkyl chain or equivalent environment. **Note:** The strong IR peak at 1750 cm⁻¹ indicates the presence of a carbonyl group, likely an ester or ketone, which influences the chemical environment of the hydrogen atoms in the molecule. **Calculation Check:** - The handwritten note "5×2 = 10 - 10 = 0" suggests a verification of the number of hydrogens in the chemical formula, confirming the spectrum accounts for all hydrogen atoms present. This analysis can assist in identifying the structure of the compound C₅H₁₀O₂ by combining the NMR and IR data.
Expert Solution
Check Mark
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY