Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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5. What effect, if any, would varying the concentration of both the aqueous species have on the
cell potentials? What about varying the size of the electrodes?
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Transcribed Image Text:5. What effect, if any, would varying the concentration of both the aqueous species have on the cell potentials? What about varying the size of the electrodes?
4.
Name
EXPERIMENT 12
ELECTROCHEMISTRY: GALVANIC CELLS
Electrodes
Use the table of standard reduction potentials from your textbook to complete the following table.
The zinc-copper Daniell cell is given as an example.
Cu
Cu
Zn
Zn
Zn
Cu
Zn
Mg
Cu
Mg
Conc. of
Each Cation
1.0 M Zn²+
0.5 M Cu²+
1.0 M Zn²+
0.1 M Cu²+
Date
1.0 M Zn²+
Zn²+ + 2e-Zn
(ag)
Half-Reactions
A. Determine the E for the Standard Zn-Cu Galvanic Cell
Zn²+
(aq)
1.0 M Cu²+
Cu²+
+2e-Cu
Cathode
B. Determine the E* for the Cu-Zn Cell at Non-standard Concentrations
1.0 M Zn²+
Anode
+ 2e → Zn
Instructor
Cu²+2e-Cu
Zn²+ + 2e → Zn
(aq)
Report Sheet
Cathode or
Anode?
Anode
E
E
(table) (calcd)
-0.76 V
+0.34 V
-0.76V
Cathode 0.34 v
anode 0.76v
Cathode 0.34 v
Cu²+ + 2e - Cul
C. Determine the E for Zn-Mg and Cu-Mg Galvanic Cells
Zn(aq) +2e Zn (s) cathode -0.76
1.0 M Mg²+Mga+2e Mg(s) anode -2.38
+1.10 V
1.10 V
1.0 M Cu²+ +Ze Cu(s) Cathode 40.34 v
2+ +2e
1.0 M Mg²+ M
Mg(s) anode -2.38v
"You must use the Nernst equation to calculate this Ecell voltage. (See Equation 8.)
1.62 v
1.10 0.98 v
Eº
(measured)
2.72v
+1.06 x
1.04 v
1.54 v
1.99 v
V
ELECTROCHEMISTRY: GALVANIC CELLS 141
M
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Transcribed Image Text:4. Name EXPERIMENT 12 ELECTROCHEMISTRY: GALVANIC CELLS Electrodes Use the table of standard reduction potentials from your textbook to complete the following table. The zinc-copper Daniell cell is given as an example. Cu Cu Zn Zn Zn Cu Zn Mg Cu Mg Conc. of Each Cation 1.0 M Zn²+ 0.5 M Cu²+ 1.0 M Zn²+ 0.1 M Cu²+ Date 1.0 M Zn²+ Zn²+ + 2e-Zn (ag) Half-Reactions A. Determine the E for the Standard Zn-Cu Galvanic Cell Zn²+ (aq) 1.0 M Cu²+ Cu²+ +2e-Cu Cathode B. Determine the E* for the Cu-Zn Cell at Non-standard Concentrations 1.0 M Zn²+ Anode + 2e → Zn Instructor Cu²+2e-Cu Zn²+ + 2e → Zn (aq) Report Sheet Cathode or Anode? Anode E E (table) (calcd) -0.76 V +0.34 V -0.76V Cathode 0.34 v anode 0.76v Cathode 0.34 v Cu²+ + 2e - Cul C. Determine the E for Zn-Mg and Cu-Mg Galvanic Cells Zn(aq) +2e Zn (s) cathode -0.76 1.0 M Mg²+Mga+2e Mg(s) anode -2.38 +1.10 V 1.10 V 1.0 M Cu²+ +Ze Cu(s) Cathode 40.34 v 2+ +2e 1.0 M Mg²+ M Mg(s) anode -2.38v "You must use the Nernst equation to calculate this Ecell voltage. (See Equation 8.) 1.62 v 1.10 0.98 v Eº (measured) 2.72v +1.06 x 1.04 v 1.54 v 1.99 v V ELECTROCHEMISTRY: GALVANIC CELLS 141 M
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