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- For the alid- cate R of the fall owing nuing Cate propose a meeheni'sm y Zeal ving calreparagd openin lactonc by g me thahal- use H-Bor on acid and B its con jugate base. 6. CH3alt Cat-TsolfWhat is the product from the following reaction? H. HO A C n-BuLi THF, -78°C; NH4CI (sat. aq.) H I D D HO B ?? E OHWhat is the structure of compound A? 010 Compound A tot 01 Oll O III O IV OV || s ||| Compound A IV COOH
- Draw the product formed when phenylacetaldehyde (CsH;CH,CHO) is treated with each reagent. Phenylacetaldehyde is partly responsible for the fragrance of the flowers of the plumeria tree, which is native to the tropical and subtropical Americas. e. Ph;P=CHCH3 f. (CH),CHNH2, mild acid g. (CH,CH)NH, mild acid h. CH,CH,OH (еxсess), H' а. NaBHa, CH,Oн b. [1] LIAIH4; (2] H20 c. [1] CH;MgBr; [2] H2O i. NH, mild acid d. NaCN, HCI j. HOCH,CH;OH, H*Which of the following is the structure of the acid chloride that is formed in the reaction shown in the box? SOCI, HO. OH sebacic acid CI CI CI C) D) CIOS SOCI B)What is the best reason why carboxylic acid 3 is the most acidic? aioH cioH а он дон CI- OH OH 1 || F ||| IV A) It is the least sterically hindered. B) The F groups are good leaving groups. C) F is very electronegative and can stabilize a negative charge as FO. D) F is very electronegative and will help to stabilize a negative charge on oxygen via induction. E) The conjugate base is stabilized by resonance.
- 2. Rank the following carboxylic acids by increasing acidity. -COOH - 4 botesupor as amor no soubor noi si sbiv Br & (zaslo COOH 1 4 OCUS COOH F 3 coin ou COOHThe boiling points of a range of organic compounds (A-D) of similar Mol. Wt.s are given below. OH OMe A в D b.p. 46-50°C Explain why the boiling point of C is higher than that of D. Explain why the boiling point of B is higher than that of A. Explain why the boiling point of C is higher than that of A. Which of these four compounds is most acidic? What makes it so acidic? b.p. 78'C b.p. 141'C b.p. 79'C (i) (ii) (iii) (iv)1. Rank each set of three alcohols in terms of increasing acidity, "1" being least acidic, and "3" being most acidic. goos CCI3 CI3C. Cl3 а. ОН ОН OH b. OH ОН ОН OH С. HO