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- 1. Write down the unique reactions in organometallic chemistry with suitable examples. 2. Why co-ordination compounds became more colorful in solution form then normal organic compounds. Please help with (iv) iv) The structure of C and D Please note: The question was cut off.at what condition we can isobutylene as an ideal gas?and why?
- The figure can rotate the plane of polarized light by 4.52 counterclockwise, 1. what is its configuration based on optical activity, 2. what is the absolute and relative configuration of the figure and 3. what is the angle of rotation of the plane-polarized light of its ENANTIOMER20. Identify each asymmetric carbon atom in the following examples, and determine (if chiral) the (R) or the (S) configuration. 21. Explain the terms with suitable examples: (a) Inductive and Field effects (b) Electromeric effect (c) Mesomeric effect (d) l-strain (e) B-strain (f) F-strain and (g) Hyperconjugation. 22. Draw the energy diagram of thermodynamic control and kinetic control of a reaction. 23. How can you classify the major reactive intermediates in organic chemistry? Give examples. 24. Write the mechanism of the following reaction: CH,OH Br 25. Write a rational mechanism for the reaction of 2-Methyl-2-butanol with a strong acid. 26. 1-Butanol is heated with HBr. Write the detailed mechanism of the reaction. 27. 2-Bromobutane is heated with NaOH. Write the detailed mechanism of the reaction.5. Which of compounds is likely to adopt a planar conformation? Why? .. A. С. D. В.
- Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? AChemistry Can anyone answer the question I circled please. Asymmetric Dihydroxylation K. Barry Sharpless, discoverer of asymmetric epoxidation, also developed asymmetric dihydroxylation reaction: OH AD-mix B OH Explain in detail: . What are the ingredients in AD-mix ß and what is the role of each ingredient? Draw structures and explain its role in the reaction.. ● Look up the stereoselectivity model for this reaction and demonstrate how it is used to predict stereochemistry of asymmetric dihydroxylation. Predict stereochemistry of the reaction above. ● Assign absolute configuration of both chirality centers in the major product.Org. Chem. 1. EA26. Can you please draw out all four , and explain what a stereoisomer is in relation ? Thanks
- ences] Use the References to access important values if needed for this question. Draw the organic product that is expected to form when the following compound is oxidized under biological conditions. oxidation CH,CH,SH reduction • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. C. opy aate Pre ChemDoodle"The application of carbon isotope data in organic geochemistry them. are grouped into two broad types. Name14. a) What isomerism is shown by butenedioic acid and why? b) Differentiate between racemic mixture and meso compound.