Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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4. An unknown aromatic compound (C₂H₁₁NO₂) displays the following ¹H and ¹³C APT NMR
spectra. Determine the structure and draw this compound to the right of each spectrum.
Label the unique sets of protons and carbons on the corresponding structures and then use
those numbers to label the NMR signals. Hint: The 2 broad singlets in the ¹H NMR make up
the NH₂ of an amide group.
9
HSP-43-829
d
td
1-H
bs
bs
170 160
T
13C APT NMR
8
T
140
7
6
T
5
ppm
120 110
4
3
-N
2
60
1 T 1
1
0
20
0 ppm
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Transcribed Image Text:4. An unknown aromatic compound (C₂H₁₁NO₂) displays the following ¹H and ¹³C APT NMR spectra. Determine the structure and draw this compound to the right of each spectrum. Label the unique sets of protons and carbons on the corresponding structures and then use those numbers to label the NMR signals. Hint: The 2 broad singlets in the ¹H NMR make up the NH₂ of an amide group. 9 HSP-43-829 d td 1-H bs bs 170 160 T 13C APT NMR 8 T 140 7 6 T 5 ppm 120 110 4 3 -N 2 60 1 T 1 1 0 20 0 ppm
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