Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- When 15.8 g KBr(s) dissolves in 119.7 g of water at 24.2°C, the final temperature of the solution comes to 21.1°C. Assume the heat capacity of the solution is roughly 4.18 J/(g·°C). What is the molar enthalpy of a solution of potassium bromide (119.00 g/mol)?arrow_forwardPotassium nitrate, KNO 3, has a molar mass of 101.1 g/mol. In a constant-pressure calorimeter, 41.8 g of KNO3 is dissolved in 277 g of water at 23.00 °C. KNO3(s) H₂O K+(aq) + NO3(aq) The temperature of the resulting solution decreases to 20.90 °C. Assume that the resulting solution has the same specific heat as • water, 4.184 J/(g · °C), and that there is negligible heat loss to the surroundings. How much heat was released by the solution? Isoln = What is the enthalpy of the reaction? AH rxn = KJ kJ/molarrow_forward4. The reaction of 250.0 mL of a 1.00 M hydrochloric acid solution with 250.0 mL of a 1.00 M sodium hydroxide solution was carried out in a constant pressure calorimeter. The total heat capacity of the calorimeter plus solutions was 6.45 kJ/K. The temperature of the calorimeter and solutions increased by 2.11°C. What is AH (in kJ) for the neutralization of 1.00 mol HCl(aq) by NaOH(aq)? A) -54.4 B) -21.2 +12.6 +54.4 E) -12.6arrow_forward
- THe G.R.A.S.P. methodarrow_forwardA bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. In an experiment, a 1.4710 g sample of maleic acid (C4H4O4) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1159 g of water. During the combustion the temperature increases from 22.46 to 25.59 °C. The heat capacity of the calorimeter, not including the surrounding water, was determined in a previous experiment to be 852.2 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of maleic acid based on these data. Assuming that no energy is lost to the surroundings, what is the molar heat of combustion of maleic acid, based on these data? (in kJ/mol). C4H4O4(s) + 3O2(g) → 2 H2O(l) + 4 CO2(g) + Energyarrow_forwardA 1.75 g sample of zinc metal is reacted with 128 g of 1.10 M hydrochloric acid solution in a constant-pressure calorimeter. The resulting solution changes in temperature from 22.58 °C to 22.97 °C. The hydrochloric acid is in excess. Based on this information, and estimating the solution's heat capacity as 4.18 Jg1 °C, what is the amount of heat, in joules, transferred in this reaction?arrow_forward
- A quantity of 85.0 mL of 0.600 M HCl is mixed with 85.0 mL of 0.600 M KOH in a constant-pressure calorimeter. The initial temperature of both solutions is the same at 17.35°C, and the final temperature of the mixed solution is 19.02°C. What is the heat capacity of the calorimeter? Assume that the specific heat of the solutions is the same as that of water and the molar heat of neutralization is −56.2 kJ/mol.arrow_forwardIron has a specific heat capacity of 0.444J/g-C. 50.0 g of iron at 35C is added to 50.0 g of water with a specific heat capacity of 4.184 J/g-C. When the temperature of the resulting mixture stops changing, the temperature is closer to that of the original water than to the iron. True or false?arrow_forward100.0 mL of 1.00 M HBr at 22.5 °C is combined with 100.0 mL of 1.00 M LiOH at 22.5 °C. The mixture reaches a temperature of 29.2 °C. Assume the density of the solutions is 1.00 g/mL and their specific heat capacity is the same as pure water. What is the molar heat of reaction?arrow_forward
- Determine the change in enthalpy (H, in J) transferred when 8.0 g of sucrose (C12H22O11)are dissolved in 92.0 g of water in a coffee cup calorimeter. The temperature of the solution changesfrom 15.0 °C to 14.7 °C Assume the process takes place at constant pressure, the masses areadditive, and the specific heat of the solution is 4.18 J/g∙°C.arrow_forwardIn a constant‑pressure calorimeter, 60.0 mL of 0.320 M Ba(OH)2 was added to 60.0 mL of 0.640 M HCl.The reaction caused the temperature of the solution to rise from 24.50 ∘C to 28.86 ∘C. If the solution has the same density and specific heat as water (1.00 g/mLand 4.184J/g⋅°C, respectively), what is ΔH for this reaction (per mole H2O produced)? Assume that the total volume is the sum of the individual volumes. ΔH= _________ kJ/mol H2Oarrow_forwardA 25.0 mL portion of dilute HCl (aq) is combined with a 25.0 mL portion of dilute NaOH in a coffee-cup calorimeter. Both solutions are initially at a temperature of 23.3 ºC. The reaction produces enough heat to raise the final temperature of the 50.0 mL of liquid in the calorimeter to 25.3 ºC . What is qrxn in J? Assume the density of the reaction mixture is 1.0 g/mL and the specific heat of the solution is 4.184 J/g· ºCarrow_forward
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