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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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
Transcribed Image Text:4. (3) For each of the following reactions, fill in the missing reagents from the list provided for the
formation of the product shown. Sequential steps, if necessary, should be numbered. Reagents
may be used more than once.
Reagent List:
Lit
NaH NaNH2
Na+
H,C-S-CI
HBr
PBr3
H20
Br2
Li-CH3
но
NaOH
Br-CH3
KBr
(HOAC)
(pyridine)
(LDA)
(MSCI)
но
Br. Br
5. (5) In reaction A, the product was determined to be racemic (both enantiomers were formed).
(a) Propose a curved arrow mechanism for reaction A that accounts for this observation.
(b) Predict the product for reaction B where conditions now use a different chloride source.
b)
H-CI
но
CI
1. LICI
2. HCI
reaction A
reaction B
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- Compounds containing deuterium (D = 2H) are useful for kinetic studies and metabolic studies with new pharmaceuticals.One way to introduce deuterium is by using the reagent LiAlD4, equivalent in reactivity to LiAlH4. Show how to makethese deuterium-labeled compounds, using LiAlD4 and D2O as your sources of deuterium, and any non-deuterated startingmaterials you wish.(a) CH3CHDOH (b) CH3CD2OH (c) CH3CD2ODarrow_forwardThe following reaction could produce an isomeric mixture of three alkenes. Please answer the following questions.arrow_forwardBelow is a selection of reactions; you may not need all of themarrow_forward
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