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- Hydrolysis of an acetal in an acid solution would yield O a) an aldehyde, a ketone, and one alcohol b) an aldehyde, a ketone, and two alcohols c) an aldehyde or a ketone and one alcohol O d) an aldehyde or a ketone and two alcohols2) Provide structures for the following compounds: a) ethyl acetate b) Pentanoic acidComplete the following syntheses – they may be two- or three-step processes. Include any necessary catalysts or reaction conditions. c) Prepare methyl ethanoate from ethanol and methanol
- Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in which there is one hydroxyl group and one ether-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction in Chapter 16. Draw structural formulas for the hemiacetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.Complete the following syntheses – they may be two- or three-step processes. Include any necessary catalysts or reaction conditions. a) Prepare propanone from 1-propanolDescribe the procedures on how will you prepare an alcohol from an alkene.
- What reagent would you use to distinguish between the aldehydes and ketones and indicate what you would observe3) Which one(s) of the following is/are an acetal ?Alkyl sulfonates undergo the same type of substitution reactions as alkyl halides and can also be prepared from alcohols. What advantage does the preparation of an alkyl sulfonate from an alcohol have over the preparation of an alkyl halide from an alcohol?
- 1. Esters can be formed by the condensation of a carboxylic acid with the hydroxyl group of an alcohol or phenol. a) Use structures to show the condensation of acetic acid (IUPAC: ethanoic acid) with the hydroxyl of cyclohexanol. b) Explain why 'condensation' is an appropriate name for this reaction. c) You'll synthesize the ester in aspirin by condensing the phenol group of salicylic acid not with acetic acid, but with acetic anhydride. Explain why the experiment calls for the use of an anhydride, rather than an acid.Which of the isomeric C4H₁0O alcohols can be prepared by hydrogenation of aldehydes? Which can be prepared by hydrogenation of ketones? Which cannot be prepared by hydrogenation of a carbonyl compound?Complete the following syntheses – they may be two- or three-step processes. Include any necessary catalysts or reaction conditions. b) Prepare ethanoic acid from ethene