35 Thioesters LR- R-Ċ-o-R' OH + R'-OH H,O acid alcohol ester R-C-OH R-SH R-Ċ-s-R’ + H,O + acid thiol thioester ott A thioester is formed from a carboxylic acid O=U 0=

Organic Chemistry
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ISBN:9781305080485
Author:John E. McMurry
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Chapter15: Benzene And Aromaticity
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Problem 24AP: Look at the three resonance structures of naphthalene shewn in Section 15-6, and account for the...
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Thioesters
||
-0-R’ +
.R
-C-
OH
R'-OH
H,O
+
acid
alcohol
ester
R
OH
R-SH
R-Ċ-S-R’ + H,O
+
acid
thiol
thioester
ott
36
A thioester is formed from a carboxylic acid
and a thiol.
• Thioesters are also called thiol esters to
emphasize that they are derivatives of thiols.
O 2017 Pearson Education, Inc.
Transcribed Image Text:Thioesters || -0-R’ + .R -C- OH R'-OH H,O + acid alcohol ester R OH R-SH R-Ċ-S-R’ + H,O + acid thiol thioester ott 36 A thioester is formed from a carboxylic acid and a thiol. • Thioesters are also called thiol esters to emphasize that they are derivatives of thiols. O 2017 Pearson Education, Inc.
(34
NHz
Ht
oH
O 2017 Pearson Education, Inc.
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Addition of HX
alkene
terminal alkyne
R-C-c-H + H-x
R-C-c-H
(HX - HCI, HBr, or HD
Addition of 1 Mole of Halogen
R-CC-R X
X, - C,or Be)
Euanple
CHJCH,
CHCH-C-c-H+ B,
Addition of 2 Moles of Halogen
R-C=C-R + 2X
(X, = Cl, er Br)
Chapter 9 Alkynes Part II (CHEM-241
Spring 2020)
Tiger Chemistry · 232 views · 11 months ago
Transcribed Image Text:(34 NHz Ht oH O 2017 Pearson Education, Inc. Tiger Chemistry SUBSCRIBED 57 subscribers Comments are turned off. Learn more Addition of HX alkene terminal alkyne R-C-c-H + H-x R-C-c-H (HX - HCI, HBr, or HD Addition of 1 Mole of Halogen R-CC-R X X, - C,or Be) Euanple CHJCH, CHCH-C-c-H+ B, Addition of 2 Moles of Halogen R-C=C-R + 2X (X, = Cl, er Br) Chapter 9 Alkynes Part II (CHEM-241 Spring 2020) Tiger Chemistry · 232 views · 11 months ago
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