Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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190x3
3.1.2 The conformations of cycloalkanes
Construct a model of cyclohexane (C6H12), a six-membered ring of carbon atoms with two
hydrogen atoms attached to each carbon atom.
Is the ring planar or puckered?
1.
(a)
55
(b)
The cyclohexane ring can be arranged in many forms. The two major forms are commonly
called the chair conformation and the boat conformation. For instance in the chair
conformation; consider the two hydrogen atoms at each carbon. One C-H bond is roughly in
the mean plane of the molecule and one C-H bond is roughly perpendicular to that plane.
These two positions are referred to, respectively, as equatorial and axial, as shown below.
axial bond
H
equatorial bond
Hequatorial H
axial H
wallon
(i) Arrange the model in the chair form. Clearly add and label the axial (a) and equatorial (e)
hydrogens on the sketch of the chair confirmation below.
emend
bundano
(c) Arrange the model in the boat form. Clearly add and label the axial (a) and equatorial (e)
hydrogens on the sketch below.
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Transcribed Image Text:190x3 3.1.2 The conformations of cycloalkanes Construct a model of cyclohexane (C6H12), a six-membered ring of carbon atoms with two hydrogen atoms attached to each carbon atom. Is the ring planar or puckered? 1. (a) 55 (b) The cyclohexane ring can be arranged in many forms. The two major forms are commonly called the chair conformation and the boat conformation. For instance in the chair conformation; consider the two hydrogen atoms at each carbon. One C-H bond is roughly in the mean plane of the molecule and one C-H bond is roughly perpendicular to that plane. These two positions are referred to, respectively, as equatorial and axial, as shown below. axial bond H equatorial bond Hequatorial H axial H wallon (i) Arrange the model in the chair form. Clearly add and label the axial (a) and equatorial (e) hydrogens on the sketch of the chair confirmation below. emend bundano (c) Arrange the model in the boat form. Clearly add and label the axial (a) and equatorial (e) hydrogens on the sketch below.
#
3
DII
(d)
56
Which conformation of cyclohexane do you think is more stable, the chair or the boat? Explain
your answer.
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Transcribed Image Text:# 3 DII (d) 56 Which conformation of cyclohexane do you think is more stable, the chair or the boat? Explain your answer.
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