3. How could you prepare hexan-2-one from the following starting materials? (a) OH (b) CH3CH₂CH₂CH₂C=CH CH3CH₂CH₂CH₂CHCH3 CH3 CH3CH₂CH₂CH₂C=CH₂ 4. How might you prepare the following alcohols from an aldehyde or ketone? Show all possibilities. (a) (b) HO H OH CH₂CH₂OH (c) CH3 CH3 5. The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 180 is also available. When a ketone or aldehyde is dissolved in H₂O, the isotopic label becomes incorporated into the carbonyl group: R₂C=0 + H₂O → R₂C=O + H₂O. Explain. (c)
3. How could you prepare hexan-2-one from the following starting materials? (a) OH (b) CH3CH₂CH₂CH₂C=CH CH3CH₂CH₂CH₂CHCH3 CH3 CH3CH₂CH₂CH₂C=CH₂ 4. How might you prepare the following alcohols from an aldehyde or ketone? Show all possibilities. (a) (b) HO H OH CH₂CH₂OH (c) CH3 CH3 5. The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 180 is also available. When a ketone or aldehyde is dissolved in H₂O, the isotopic label becomes incorporated into the carbonyl group: R₂C=0 + H₂O → R₂C=O + H₂O. Explain. (c)
Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry
Section4.SE: Something Extra
Problem 62AP: Alcohols undergo an oxidation reaction to yield carbonyl compounds on treatment with CrO3. For...
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