3. (a) Clearly explain the three factors affecting chemical shifts (inductive effects, conjugation and magnetic anisotropy). (b) Clearly explain why acetylene, ethylene and benzene protons show their observed chemical shifts in 'H NMR. (c) Why do metal hydride protons exhibit such a high field chemical shift in the majority of the cases? when do you expect to see exceptions? (what type of metal complexes)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
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3. (a) Clearly explain the three factors affecting chemical shifts (inductive effects, conjugation
and magnetic anisotropy). (b) Clearly explain why acetylene, ethylene and benzene protons
show their observed chemical shifts in 'H NMR. (c) Why do metal hydride protons exhibit such
a high field chemical shift in the majority of the cases? when do you expect to see
exceptions? (what type of metal complexes)
Transcribed Image Text:3. (a) Clearly explain the three factors affecting chemical shifts (inductive effects, conjugation and magnetic anisotropy). (b) Clearly explain why acetylene, ethylene and benzene protons show their observed chemical shifts in 'H NMR. (c) Why do metal hydride protons exhibit such a high field chemical shift in the majority of the cases? when do you expect to see exceptions? (what type of metal complexes)
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