3) Consider the following equilibrium: 2C0(g)= C(s) + CO2 (g) Thermodynamic data are provided in table given below: AH (k] mol-) S°J K-mol-1) CO(g) C(s) CO2(g) -110.5 197.9 5.69 213.6 You may assume that AH° and AS° do not vary with temperature. -393.5 (a) Calculate the values of AH°rn and AS°rxn (b) At what temperature will an equilibrium mixture of 101.3 Pa total pressure contain the mixture in which partial pressure ratio of CO to CO2 is Pco/Pco2 = 1/99? (R = 8.314 J/mol K) %3D

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3) Consider the following equilibrium: 2C0(g) = C(s) + CO2 (g)
Thermodynamic data are provided in table given below:
AH (kJ mol) S°(J K-mol-1)
CO(g)
C(s)
CO2(g)
-110.5
197.9
5.69
213.6
-393.5
You may assume that AH° and AS° do not vary with temperature.
(a) Calculate the values of AH°rn and AS°,
(b) At what temperature will an equilibrium mixture of 101.3 Pa total pressure contain the mixture
in which partial pressure ratio of CO to CO2 is Pco/Pco2
= 1/99? (R = 8.314 J/mol K)
Transcribed Image Text:3) Consider the following equilibrium: 2C0(g) = C(s) + CO2 (g) Thermodynamic data are provided in table given below: AH (kJ mol) S°(J K-mol-1) CO(g) C(s) CO2(g) -110.5 197.9 5.69 213.6 -393.5 You may assume that AH° and AS° do not vary with temperature. (a) Calculate the values of AH°rn and AS°, (b) At what temperature will an equilibrium mixture of 101.3 Pa total pressure contain the mixture in which partial pressure ratio of CO to CO2 is Pco/Pco2 = 1/99? (R = 8.314 J/mol K)
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