3) Consider a gaseous system of N noninteracting, diatomic molecules, each having an electric dipole moment µ, placed in an external electric field of strength E. The energy of such a molecule will be given by the kinetic energy of rotation as well as translation plus the potential energy of orientation in the applied field: p? , SPe? 2 2 Po - µEcos0, 2m 21 21sin20 where I is the moment of inertia of the molecule. Study the thermodynamics of this system, including the electric polarization and the dielectric constant. Assume that (i) the system is a classical one and (ii) |µE| « kgT.
3) Consider a gaseous system of N noninteracting, diatomic molecules, each having an electric dipole moment µ, placed in an external electric field of strength E. The energy of such a molecule will be given by the kinetic energy of rotation as well as translation plus the potential energy of orientation in the applied field: p? , SPe? 2 2 Po - µEcos0, 2m 21 21sin20 where I is the moment of inertia of the molecule. Study the thermodynamics of this system, including the electric polarization and the dielectric constant. Assume that (i) the system is a classical one and (ii) |µE| « kgT.
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