2NH3(g) + 3O2(g) + 2CH4(g) 2HCN(g) + 6H2O(g) The above reaction is used in the industrial production of hydrogen cyanide. Consider the relevant thermodynamic data from the appendices of your text. (The tabulated values ΔH°f and S° are for 25°C. For the purposes of this question assume that ΔH° and ΔS° are invariant with temperature. This is not actually true but would generally be a reasonable approximation over "small" temperature ranges.) Answer the following practice questions: (a)Calculate ΔH° for this equation. (b)Calculate ΔS° for this equation. (c) Calculate ΔG° at 548°C, for this equation. (d) Are the following statements about this process True or False? The high temperature required for this process is needed for kinetic reasons. True of False? The equilibrium position for this reaction is further to the left at lower temperatures. True or False? This reaction is exothermic at room temperature. True or False? Thermodynamically, this reaction is spontaneous only above a certain temperature. True or False? At temperatures significantly lower than 1000°C this reaction is not spontaneous. True or False?

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2NH3(g) + 3O2(g) + 2CH4(g) 2HCN(g) + 6H2O(g)

The above reaction is used in the industrial production of hydrogen cyanide. Consider the relevant thermodynamic data from the appendices of your text. (The tabulated values ΔH°f and S° are for 25°C. For the purposes of this question assume that ΔH° and ΔS° are invariant with temperature. This is not actually true but would generally be a reasonable approximation over "small" temperature ranges.)

Answer the following practice questions:

(a)Calculate ΔH° for this equation.

(b)Calculate ΔS° for this equation.

(c) Calculate ΔG° at 548°C, for this equation.

(d) Are the following statements about this process True or False?

  • The high temperature required for this process is needed for kinetic reasons. True of False?
  • The equilibrium position for this reaction is further to the left at lower temperatures. True or False?
  • This reaction is exothermic at room temperature. True or False?
  • Thermodynamically, this reaction is spontaneous only above a certain temperature. True or False?
  • At temperatures significantly lower than 1000°C this reaction is not spontaneous. True or False?
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