22.64 22.64 Which compound in each of the sets shown in Fig. P22.64(b) As the above data show, the AG° for hydrolysis of Aof bromine, bromoacetone is isolatecCH3The rate of appearance of bromoacerthe following rate law:rate = k[acetoacetic aci-AG° (hydrolysis) =-67.3 kJ mol-1AG° (hydrolysis) =-30.9 kJ mol-1(The reaction rate is zero order in brcmechanism for the reaction that is cois much more negative than the AG° for hydrolysis ofphenyl acetate (B). Explain why the equilibrium for thehydrolysis of A is much more favorable than the equi-librium for the hydrolysis of B.law.22.69 Account for the fact that treatment of1,3-propanedione with I, and NaOH gtate of iodoform even though it is notBesides iodoform, the other product oacidification, is two equivalents of beris most acidic? Explain.2.65 Arrange the following compounds in order of increasingacidity and explain.(1) isobutyramideCH(2) octanoic acid1,3-diphenyl-1,3-propanedi(3) toluene(4) ethyl acetate(5) phenylacetylene(6) phenol(a)CH,CCH,CCH3,CH,CCH,CCH,PhCH3CCHCCH3,orPh(b)C-CH3CH,CH,CH,C-CH3orH2C=CHCH;Figure P22.64H;C-C-CH;-Br + HBr + CO,Н,С—С—СH, —С—ОН + Brzbromoacetoneacetoacetic acidFigure P22.68

Answered: Image /qna-images/answer/95f3dfbd-2d33-4411-9ad8-fdb9dca2a432.jpg

22.64 Which compound in each of the sets shown in Fig. P22.64 is most acidic? Explain. Besides iodoform, the c acidification, is two equ 2 65 Arrange the following compounds in order of increasing acidity and explain. (1) isobutyramide (2) octanoic acid 1,3-diphenyl- (3) toluene (4) ethyl acetate (5) phenylacetylene (6) phenol (a) CH,CCH,CCH3, CH,CCHCCH3, CH,CCH,CCH,Ph or Ph (b) or CH;CH,CH,-C-CH3 H,C=CHCH,-C-CH3 Figure P22.64

22.64 Which compound in each of the sets shown in Fig. P22.64 is most acidic? Explain. Besides iodoform, the c acidification, is two equ 2 65 Arrange the following compounds in order of increasing acidity and explain. (1) isobutyramide (2) octanoic acid 1,3-diphenyl- (3) toluene (4) ethyl acetate (5) phenylacetylene (6) phenol (a) CH,CCH,CCH3, CH,CCHCCH3, CH,CCH,CCH,Ph or Ph (b) or CH;CH,CH,-C-CH3 H,C=CHCH,-C-CH3 Figure P22.64

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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