20. Carbenes bind to metal centres synergistically, but which of these statements is/are true? 1. Metal carbene bonds are formed through overlap of the metal d-orbitals and the o orbital of the carbene. 2. Carbene ligands contain o donor and n donor character. 3. Carbene ligands are neutral ligands. Only statement 1 is true.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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20.
Carbenes bind to metal centres synergistically, but which of these statements is/are
true?
1.
Metal carbene bonds are formed through overlap of the metal d-orbitals and
the o orbital of the carbene.
2.
Carbene ligands contain o donor and n donor character.
3.
Carbene ligands are neutral ligands.
A
Only statement 1 is true.
Only statement 2 is true.
C
Only statement 3 is true.
D
Only statements 1 and 2 are true.
E
Only statements 2 and 3 are true.
Transcribed Image Text:20. Carbenes bind to metal centres synergistically, but which of these statements is/are true? 1. Metal carbene bonds are formed through overlap of the metal d-orbitals and the o orbital of the carbene. 2. Carbene ligands contain o donor and n donor character. 3. Carbene ligands are neutral ligands. A Only statement 1 is true. Only statement 2 is true. C Only statement 3 is true. D Only statements 1 and 2 are true. E Only statements 2 and 3 are true.
17.
Radical chemistry was originally used in the process for making polymers; many
limitations were quickly discovered. Which of these statements is/are true?
1.
Radical polymerisation leads to head-to-head formation of polypropene.
Radical polymerisation leads to the formation of syndiotactic polypropene.
2.
3.
Radical polymerisation forms uniform chain length polypropene.
A
All of these statements are true.
B
None of these statements are true.
C
Only statement 1 is true.
Only statement 3 is true.
Only statements 1 and 3 are true.
E
18.
How many C-0 peaks are expected in the infrared spectrum of the complex fac-
[M(CO)»Cls]?
D
E
4120m4
Transcribed Image Text:17. Radical chemistry was originally used in the process for making polymers; many limitations were quickly discovered. Which of these statements is/are true? 1. Radical polymerisation leads to head-to-head formation of polypropene. Radical polymerisation leads to the formation of syndiotactic polypropene. 2. 3. Radical polymerisation forms uniform chain length polypropene. A All of these statements are true. B None of these statements are true. C Only statement 1 is true. Only statement 3 is true. Only statements 1 and 3 are true. E 18. How many C-0 peaks are expected in the infrared spectrum of the complex fac- [M(CO)»Cls]? D E 4120m4
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