2. What is the role of Nitrogen gas in polarography ? 3. Draw and label a ideal polarogram. 4. Write a note on DME with suitable diagram. 5. Discuss the Qualitative application of polarography. 6. Draw a schematic diagram of Dropping Mercury Electm and disadvantages of DME. 7. Sketch ideal polarographic wave. Explain the term resi

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2. What is the role of Nitrogen gas in polarography ?
3. Draw and label a ideal polarogram.
4. Write a note on DME with suitable diagram.
5. Discuss the Qualitative application of polarography.
6. Draw a schematic diagram of Dropping Mercury Electrode. Give advantages
and disadvantages of DME.
7. Sketch ideal polarographic wave. Explain the term residual current and
limiting current.
8. What is residual current ?
9. Define the term migration current in polarography.
10. Give the principle of polarography and explain the role of supporting
electrolyte in polarography.
11. What is supporting electrolyte in polarography ?
12. Explain contruction and working of DME.
13. How the effect of migration current eliminated.
14. Define the term maximum supressor.
15. Sketch a neat labeled diagram of an ideal polarographic curve and explain
Residual current ,Condenser current, Faradic current and Migration current.
16. Calculate the diffusion current flowing through the cell containing the
solution of Cd²+ ions having concentration of 5 millimoles l- if the drop rate
is 4.5 seconds and rate of fallowing mercury is 4 mg sec. The diffusion
coefficient of Cd²*ion is 7 x10-6 cm² sec-'.
17.Calculate the diffusion coefficient of Cu²*ion of 2 x10-3M CUSO4 solution
shows 45µA. The mercury drop time is 3.75 second per drop and mass of Hg
flowing per second through capillary is 1.011mg s'.
18. The solution of Cd2+ ions having concentration 5 millimoles 1-. If the drop
rate is 6 seconds and rate of falling mercury is 4 mg s-'. What is the diffusion
current flowing through the cell if the diffusion coefficient of Cd²+ ion is 7.0
x10-6 cm? s-'.
19. The diffusion coefficient of Cd²+ ion having concentration 3 x10-3mols 1' is
0.72 x10-5 cm2 sl. If the capillary characteristic are t=4 sec and m=3mg s
.Calculate the diffusion current for Cd.
XXXXXX
XXXXXXX:
XXXXXXXX
Transcribed Image Text:2. What is the role of Nitrogen gas in polarography ? 3. Draw and label a ideal polarogram. 4. Write a note on DME with suitable diagram. 5. Discuss the Qualitative application of polarography. 6. Draw a schematic diagram of Dropping Mercury Electrode. Give advantages and disadvantages of DME. 7. Sketch ideal polarographic wave. Explain the term residual current and limiting current. 8. What is residual current ? 9. Define the term migration current in polarography. 10. Give the principle of polarography and explain the role of supporting electrolyte in polarography. 11. What is supporting electrolyte in polarography ? 12. Explain contruction and working of DME. 13. How the effect of migration current eliminated. 14. Define the term maximum supressor. 15. Sketch a neat labeled diagram of an ideal polarographic curve and explain Residual current ,Condenser current, Faradic current and Migration current. 16. Calculate the diffusion current flowing through the cell containing the solution of Cd²+ ions having concentration of 5 millimoles l- if the drop rate is 4.5 seconds and rate of fallowing mercury is 4 mg sec. The diffusion coefficient of Cd²*ion is 7 x10-6 cm² sec-'. 17.Calculate the diffusion coefficient of Cu²*ion of 2 x10-3M CUSO4 solution shows 45µA. The mercury drop time is 3.75 second per drop and mass of Hg flowing per second through capillary is 1.011mg s'. 18. The solution of Cd2+ ions having concentration 5 millimoles 1-. If the drop rate is 6 seconds and rate of falling mercury is 4 mg s-'. What is the diffusion current flowing through the cell if the diffusion coefficient of Cd²+ ion is 7.0 x10-6 cm? s-'. 19. The diffusion coefficient of Cd²+ ion having concentration 3 x10-3mols 1' is 0.72 x10-5 cm2 sl. If the capillary characteristic are t=4 sec and m=3mg s .Calculate the diffusion current for Cd. XXXXXX XXXXXXX: XXXXXXXX
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