2. Two mechanisms are given below for the decomposition of aryl diazonium salts in aqueous solution containing the nucleophile A". and and -NEN + H₂O 1 -NEN + A Mechanism A: -N=N + H₂O + A Mechanism B: slow fast fast REN EN + N₂ -OH + H -OH + N₂ + H² + N₂ Clearly describe how you can use each of the following type of study to determine which one is the correct mechanism (a) Kinetic (i.e. rate) studies (8 pts)

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
Section21.2: Nucleophilic Acyl Substitution Reactions
Problem 6P
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Two mechanisms are among those that have been postulated for decomposition of aryl diazonium salts in aqueous solution containing nucleophilic anions, A—:
2.
Two mechanisms are given below for the decomposition of aryl diazonium salts in
aqueous solution containing the nucleophile A".
and
and
-NEN + H₂O 1
-NEN + A
Mechanism A:
-N=N
+ H₂O
+ A
Mechanism B:
slow
fast
fast
REN
EN
+ N₂
-OH + H
-OH + N₂ + H²
+ N₂
Clearly describe how you can use each of the following type of study to determine which one is the
correct mechanism
(a) Kinetic (i.e. rate) studies (8 pts)
Transcribed Image Text:2. Two mechanisms are given below for the decomposition of aryl diazonium salts in aqueous solution containing the nucleophile A". and and -NEN + H₂O 1 -NEN + A Mechanism A: -N=N + H₂O + A Mechanism B: slow fast fast REN EN + N₂ -OH + H -OH + N₂ + H² + N₂ Clearly describe how you can use each of the following type of study to determine which one is the correct mechanism (a) Kinetic (i.e. rate) studies (8 pts)
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