2. The following mechanism has been proposed for the thermal decomposition of acetaldehyde. CH3CHO kı CH3* + CHO* k2 CH3*+ CH3CHO CH3*+ CO+ CH4 k3 CHO*+ CH3CHO CH3*+ 2CO +H2 k4 2 CH3* C2H6 a) Find the rate law for the consumption of CH3CHO. b) Find the rate law for the formation of CH4.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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2. The following mechanism has been proposed for the thermal decomposition of acetaldehyde.
CH3CHO
kı
CH3* + CHO*
k2
CH3*+ CH3CHO
CH3*+ CO+ CH4
k3
CHO*+ CH3CHO
CH3*+ 2CO +H2
k4
2 CH3*
C2H6
a) Find the rate law for the consumption of CH3CHO.
b) Find the rate law for the formation of CH4.
Transcribed Image Text:2. The following mechanism has been proposed for the thermal decomposition of acetaldehyde. CH3CHO kı CH3* + CHO* k2 CH3*+ CH3CHO CH3*+ CO+ CH4 k3 CHO*+ CH3CHO CH3*+ 2CO +H2 k4 2 CH3* C2H6 a) Find the rate law for the consumption of CH3CHO. b) Find the rate law for the formation of CH4.
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