Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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2) Flash Distillation (or Single-Stage Contact)
A mixture of 60 mole % n-heptane and 40 mole % toluene is vaporized at 101.325 kPa (absolute) until 40
moles of vapor and 60 moles of liquid in equilibrium with each other are produced. This occurs in a single-
stage system and the vapor and liquid are kept in contact until equilibrium is achieved. Calculate the
composition of the vapor and liquid.
Note: Assume the system exhibits ideal behavior (which it mostly does), e.g. Raoult's Law applies and an
Antoine's Vapor Pressure correlation is a sufficiently accurate model of component vapor pressure.
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Transcribed Image Text:2) Flash Distillation (or Single-Stage Contact) A mixture of 60 mole % n-heptane and 40 mole % toluene is vaporized at 101.325 kPa (absolute) until 40 moles of vapor and 60 moles of liquid in equilibrium with each other are produced. This occurs in a single- stage system and the vapor and liquid are kept in contact until equilibrium is achieved. Calculate the composition of the vapor and liquid. Note: Assume the system exhibits ideal behavior (which it mostly does), e.g. Raoult's Law applies and an Antoine's Vapor Pressure correlation is a sufficiently accurate model of component vapor pressure.
0
1
2
3
4
5
LO
6
7
8
9
20
21
22
23
24
25
26
27
Ready
A
B
Temperature
T (C)
98.5
99.8
101.2
102.5
103.9
105.2
106.6
107.9
109.3
110.7
EtOH-Water
71 F
Rain off and on
C
Vapor Pressure
n-heptane
kPa
101.400
105.5
109.7
114.1
118.6
123.2
127.9
132.8
137.9
143.1
n-heptane-Toluene Sheet1
D
Toluene
kPa
70.745
73.732
76.818
80.005
83.297
86.694
90.200
93.817
97.548
101.394
E
X
1.000
0.871
0.747
0.628
0.513
0.403
0.297
0.194
0.095
0.000
F
Y
1.000
0.906
0.808
0.707
0.600
0.490
0.374
0.255
0.130
0.000
HO COLO
G
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Transcribed Image Text:0 1 2 3 4 5 LO 6 7 8 9 20 21 22 23 24 25 26 27 Ready A B Temperature T (C) 98.5 99.8 101.2 102.5 103.9 105.2 106.6 107.9 109.3 110.7 EtOH-Water 71 F Rain off and on C Vapor Pressure n-heptane kPa 101.400 105.5 109.7 114.1 118.6 123.2 127.9 132.8 137.9 143.1 n-heptane-Toluene Sheet1 D Toluene kPa 70.745 73.732 76.818 80.005 83.297 86.694 90.200 93.817 97.548 101.394 E X 1.000 0.871 0.747 0.628 0.513 0.403 0.297 0.194 0.095 0.000 F Y 1.000 0.906 0.808 0.707 0.600 0.490 0.374 0.255 0.130 0.000 HO COLO G
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