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- Styles 10. Draw all the significant resonance contributors for the following molecules or ions. H. H. (a) H. H. H. (b) H,C CH, H. :ÖCH, (c) H.C :o: (d)10. E to CH3ONa a) Br₂ Br2 1. Mg /ether khan (A) (B) (C) (D) hv FeBr3 hv 2. CO2 3. H3O+ C1 B2 B3 B1 KMnO4 H+ C1 Mg, ether CHO b) 1. CH3Mgl H2SO4 HBr 1. Mgether khan A B D to 2. H3O+ peroxide 2. H₂C-CH2 ° CH3COCI AICI 3 1. C1 1. 03 G F E 2. H3O+ 2. Na₂S 3. H3O+2. The molecular structure of perylene (see below) contains 20 m-electrons, which is not a Hückel number. Nonetheless, this compound is aromatic. Explain. 88 perylene
- Select the best answer that identifies which of the following compound(s) are aromatic. H. H. H. 3 7. a.) 1, 2, 4, 5 b.) 3, 4, 7 c.) 1, 2, 5, 6 d.) 2, 4, 5, 7 e.) Both b.) and c.)Fundamentals. 1. Complete each part below. s fo olad irroda anonaen Isoiatedo owi ar to das nl (i i) Identify both the C/H types (1°, 2°, 3°, 4° or NA) on the molecule below: ar ord boa stibomo S-CH3 CH3 CH3 H3C-C▬▬CH2-CH-CH,-CH- CH3 CHз-CH2Looking for compound B and E . Thank You
- 4. :Ö N-Phenylsydnone, so-named because it was first studied at the University of Sydney, Australia, behaves like a typical aromatic molecule. Explain, using the Hückel 411 + 2 rule. H N 2-2 Z-1 :0-N N N-Phenylsydnone :0: :0 :0 H N 2: N- 2=Draw a molecular orbital diagram for the pi system of tetrazole (including the piacemen oi iis pi electrons) and provide an analysis of its aromaticity using Hückel's rule denoting whether tetrazole is in fact aromatic, antiaromatic, or nonaromatic. H N° Tetrazole b. Provide a picture of the Highest occupied Molecular Orbital (HOMO) and the Lowest Unnocupied Molecular Orbital (LUMO) of tetrazole depicting the phases of thep orbitals, the bonding, antibonding, and non-bonding interactions.O (1) H20, H*; (2) Jones reagent (1) H20, H*; (2) PCC, CH2CI2 (1) conc. H2SO4: (2) Jones reagent O (1) H20, H*; (2) Tollens reagent (1) conc. H2SO4: (2) PCC, CH2CI2 O (1) conc. H2SO4: (2) Tollens reagent
- Which structure is consistent with this 'H NMR spectrum? (1.2 ppm, triplet, 3H); (1.9 ppm, singlet, 3H); (4.2 ppm, quartet, 2H) A. H3C С. но D. C. B.2) Which one of the following molecules is anti-aromatic? a. b. C. d. e.1. With regards to the following heterocycles, please answer the questions below: A 'N' 1 2 4 -N A HH 6. 7 9 10 + .N N. 11 12 13 14 15 нн 16 17 18 19 a) Define which of the heterocycles is aromatic, non aromatic, or antiaromatic. Small TIP: write down all the lone pairs on heteroatoms before applying Hückel's rule. b) Provide the IUPAC names for heterocycles 1, 4-5, 8, 10. c) Provide the common name for heterocycles 1, 4-5, 8, 10-11, 14-15, 19-20. 20 IzJ