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- a. b. 22.16 Using ammonia as your source of nitrogen, show the reagents you would use to prepare each of the following amines: C. d. e. O f. PRACTICE the skill H Answer xi -N -NH₂ H O 1) [H*] NaBH₂CN NH3 2) [H*] NaBH3CN CH3CHO16.13 Name each of the following amines by one of the methods used in Exercises 16.7, 16.9, and 16.11: a. CH₁₂ CH-C-NH, C. NH, CH₁₂ b. CH,CH,-N-CH₂CH, d. Cl CH, NH CH,CHCH,CHCH,22.2 Nomenclature of Amines Which of the following correctly names the compound shown? H₂C. CI O ethyl ethyl -methyl-4-chloro-3- methylaniline O4-chloro- ethyl ,3- dimethylaniline ethylmethyl-1-amino-4-chloro- 3-methylbenzene O 4-chloro-1-ethyl-1,3- dimethylaniline
- 20.60 How would you convert benzoic acid (C6H5CO₂ H) to each compound? a. of b. C. HO d. OxAnswer the following questions about atomoxetine, a drug used to treatattention deficit hyperactivity disorder (ADHD). a.) What amides can be reduced to form atomoxetine?b.) What starting materials can be used to form atomoxetine by reductiveamination? Draw all possible methods.c.) What products are formed by Hofmann elimination of atomoxetine?MC 10 How many equivalents of LiAIH4 do the following molecules require for their conversion to amines? a. A: 2 equiv.; b. A: 1 equiv.; c. A: 1 equiv.; c. A: 2 equiv.; A: 2 equiv.; e. A •C=N B: 2 equiv.; B: 2 equiv.; B: 1 equiv.; B: 4 equiv.; B: 3 equiv.; C: 2 equiv.; C: 3 equiv.; C: 2 equiv.; C: 3 equiv.; C: 3 equiv.; B NH₂ D: 2 equiv.; D: 4 equiv.; D: 2 equiv.; D: 2 equiv.; D: 3 equiv.
- 18.35 Draw the structure of each ammonium salt. a. dipropylammonium chloride b. butylammonium bromide c. ethyldimethylammonium hydroxide 13Water intoxication is most likely to be a problem among users of: a. SSRIs b. traditional antipsychotics with low anti-ACh activity c. benzodiazepines d. traditional antipsychotics with high anti-ACh activity e. MAOIs f. a and e18.61 Below are two hypothetical compounds. -S N. N. (a) Which compound would you expect to hold greater promise as a potential antihistamine? Explain your choice. (b) Do you expect the compound you chose (in part a) to exhibit sedative properties? Explain your reasoning.
- 15.54 Draw condensed formulas for the carboxylic acid and amine that form the following amides: (a) H3C- CH2-C-NH2 (b) (c) HC-NH-16.41) Give on IUPAC or common home for each compound. 2 b. in O d. Hon de jha ok C. e- ion ganho-to- 0 y. ho Y 2-ethylbutonoyl chloride methyl benzoate N-ethyl-N-methylpropion amide ethyl formale benzoic propionic anhydride isopropyl 3-ethyl hexanoateBarbiturates with rapid onset and short duration are: O used to treat epilepsy. O not used medically. O used as anesthetics. less addictive.