16.31 The reaction n-C,H,Br + S,O?- → C,H,S,O; + Br in aqueous solution is first order in C,H,Br and first-order in S,0?-. At 37.5°C, the following data were obtained (where 1 mol/dm3 and 1 ks c° 103 s): 10°[S,O?¯]/c° 90.4 86.3 76.6 66.8 96.6 t/ks 1.110 2.010 5.052 11.232 The initial C,H,Br concentration was 39.5 mmol/dm³. Find the rate constant using a graphical method.

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16.31 The reaction n-C,H,Br + S,O?¯ →→ C¿H¬S,O; + Br¯
in aqueous solution is first order in C,H,Br and first-order in
S,O?-. At 37.5°C, the following data were obtained (where
3,
c° = 1 mol/dm³ and 1 ks
= 103 s):
10°[S,O}-/c°
96.6
90.4
86.3
76.6
66.8
t/ks
1.110
2.010
5.052
11.232
The initial C,H,Br concentration was 39.5 mmol/dm³. Find the
rate constant using a graphical method.
Transcribed Image Text:16.31 The reaction n-C,H,Br + S,O?¯ →→ C¿H¬S,O; + Br¯ in aqueous solution is first order in C,H,Br and first-order in S,O?-. At 37.5°C, the following data were obtained (where 3, c° = 1 mol/dm³ and 1 ks = 103 s): 10°[S,O}-/c° 96.6 90.4 86.3 76.6 66.8 t/ks 1.110 2.010 5.052 11.232 The initial C,H,Br concentration was 39.5 mmol/dm³. Find the rate constant using a graphical method.
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