16. In acid solution, chlorate(V) ions, CIO3 slowly oxidize chloride ions to chlorine. The following kinetic data are obtained at 25 °C. [CIO3]/ M [Cl] /M 0.15 [H*]/ M Experiment Initial rate / M s-' 1.0 x 105 4.0 x 10-5 8.0 x 10-5 1 0.08 0.20 0.08 0.15 0.40 3 0.16 0.15 0.40 4 0.08 0.30 0.20 2.0 x 10-5 Determine the order of the reaction with respect to each reactant.

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Chapter11: Chemical Kinetics
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16. In acid solution, chlorate(V) ions, ClO3 slowly oxidize chloride ions to chlorine. The
following kinetic data are obtained at 25 °C.
[CIO3]/ M
[Cl] / M
Initial rate / M s-
1.0 x 10-5
4.0 x 10-5
8.0 x 10-5
Experiment
[H*]/M
0.20
1
0.08
0.15
2
0.08
0.15
0.40
3
0.16
0.15
0.40
4
0.08
0.30
0.20
2.0 x 10-5
Determine the order of the reaction with respect to each reactant.
Transcribed Image Text:16. In acid solution, chlorate(V) ions, ClO3 slowly oxidize chloride ions to chlorine. The following kinetic data are obtained at 25 °C. [CIO3]/ M [Cl] / M Initial rate / M s- 1.0 x 10-5 4.0 x 10-5 8.0 x 10-5 Experiment [H*]/M 0.20 1 0.08 0.15 2 0.08 0.15 0.40 3 0.16 0.15 0.40 4 0.08 0.30 0.20 2.0 x 10-5 Determine the order of the reaction with respect to each reactant.
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