15. Suppose that we titrate 100.0 mL of 0.050 0 M Fe²+ with 0.100 M Ce*“, using the cell as shown here. The equivalence point occurs when V=50.00 mL The titration reaction: Ce4++ Fe²+ Buret containing Ce** V Ce+ + Fe+ E° (Ce**/Ce³*) = 1.70 V; E° (Fe³*/Fe²+) = 0.767 V, EsCE= 0.241 V Calculate the cell voltage at 66.0 mL of Ce**. Calomel reference electrode Pt wire Fe* in 1 M HCIO, Magnetic stirring bar

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Potentiometric Titrations

Potentiometric titration is one of the important titration methods and is mainly carried out to characterize acid solutions. It follows a method similar to that of the normal titration technique, but the main difference is that there is no indicator used in the potentiometric titrations. Instead of using an indicator, electrodes are employed for monitoring the whole titration process. A scientist named Robert Behrend did the potentiometric titration for the first time, and it was done using the mercurous solution and potassium chloride.