15 A mixture of 1773 g of water and 227 g of ice is in an initial equilibrium state at 0.000°C. The mixture is then, in a reversible process, brought to a second equilibrium state where the water-ice ratio, by mass, is 1.00:1.00 at 0.000°C. (a) Calculate the entropy change of the system during this process. (The heat of fusion for wa- ter is 333 kJ/kg.) (b) The system is then returned to the initial equi- librium state in an irreversible process (say, by using a Bunsen burner). Calculate the entropy change of the system during this process. (c) Are your answers consistent with the second law of thermodynamics?

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15 A mixture of 1773 g of water and 227 g of ice is in an initial
equilibrium state at 0.000°C. The mixture is then, in a reversible
process, brought to a second equilibrium state where the water-ice
ratio, by mass, is 1.00:1.00 at 0.000°C. (a) Calculate the entropy
change of the system during this process. (The heat of fusion for wa-
ter is 333 kJ/kg.) (b) The system is then returned to the initial equi-
librium state in an irreversible process (say, by using a Bunsen
burner). Calculate the entropy change of the system during this
process. (c) Are your answers consistent with the second law of
thermodynamics?
Transcribed Image Text:15 A mixture of 1773 g of water and 227 g of ice is in an initial equilibrium state at 0.000°C. The mixture is then, in a reversible process, brought to a second equilibrium state where the water-ice ratio, by mass, is 1.00:1.00 at 0.000°C. (a) Calculate the entropy change of the system during this process. (The heat of fusion for wa- ter is 333 kJ/kg.) (b) The system is then returned to the initial equi- librium state in an irreversible process (say, by using a Bunsen burner). Calculate the entropy change of the system during this process. (c) Are your answers consistent with the second law of thermodynamics?
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