Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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This problem is (13.20) from a book  "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

13.20. At one bar, a mixture of mole fractions 0.20, 0.45, 0.25, and 0.10 of n-hexane,
n-heptane, iso-heptane, and n-octane, respectively, is prepared. The saturation
pressure of each species can be modeled by the equation log10Pvap=c
C2/(c3T), where Pap has units of mmHg, T has units of °C, and the constants
Ci, C2, and c are given by Table 13.1
Table 13.1 Values of the constants c1, c2, and c3
Species
С2
C3
С1
n-hexane
6.87024
1168.72
224.210
n-heptane
iso-heptane
6.89385
1264.37
216.636
1236.03
6.87318
219.545
6.90940 1349.82
209.385
n-octane
(a) Find the bubble-point temperature of this mixture and the corresponding
vapor-phase compositions
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Transcribed Image Text:13.20. At one bar, a mixture of mole fractions 0.20, 0.45, 0.25, and 0.10 of n-hexane, n-heptane, iso-heptane, and n-octane, respectively, is prepared. The saturation pressure of each species can be modeled by the equation log10Pvap=c C2/(c3T), where Pap has units of mmHg, T has units of °C, and the constants Ci, C2, and c are given by Table 13.1 Table 13.1 Values of the constants c1, c2, and c3 Species С2 C3 С1 n-hexane 6.87024 1168.72 224.210 n-heptane iso-heptane 6.89385 1264.37 216.636 1236.03 6.87318 219.545 6.90940 1349.82 209.385 n-octane (a) Find the bubble-point temperature of this mixture and the corresponding vapor-phase compositions
(b) Find the dew-point temperature and the corresponding liquid-phase
compositions
(c) At 92 °C, find both the liquid and vapor compositions and the fraction of the
system that is vapor
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Transcribed Image Text:(b) Find the dew-point temperature and the corresponding liquid-phase compositions (c) At 92 °C, find both the liquid and vapor compositions and the fraction of the system that is vapor
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