13. Compound 1 is an acetyl protected precursor of the phytonutrient pterostilbene (2), a natural antioxidant founs blueberries. Which reagents would you use to synthesize 1 starting with 3 and 4? Shal A) PhB(OH)2, K:CO₂ B) Pd(OAC)2, 2 PPh₁, K₂CO C) Cul, H₂O/H₂0 D) NaOEt/EtOH 14. Which is a D-sugar? .O HO- HOH HO-H A HO H H CH₂OH A 15. Which of these compounds is the best Michael acceptor? A HO- --H HO-H H- -OH HO-H CH₂OH B 16. What is the final product of this reaction sequence? B B CI SO₂H NaCN DMSO . This compound does not undergo Diels-Alder reactions ber A) It lacks electron-withdrawing groups B) it lacks strong electron C) It cannot al HO- HOH -H H-OH H- da C 2 in -OH CH₂OH C 70% H₂SO4 reflux HO -H HOH H-OH -H CH₂OH D HO- OH 3. D OH

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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13. Compound 1 is an acetyl protected precursor of the phytonutrient pterostilbene (2), a natural antioxidant founs
blueberries. Which reagents would you use to synthesize 1 starting with 3 and 4?
Sal
A) PhB(OH)2, KCO₁
B) Pd(OAC)2, 2 PPh₁, K₂CO
C) Cul, H₂O/H₂0
D) NaOEt/EtOH
14. Which is a D-sugar?
O
HO-
HOH
HO-H
HO-H
A
CH₂OH
A
H
A
HO-
--H
HO-H
H-
HO-H
15. Which of these compounds is the best Michael acceptor?
CH₂OH
B
16. What is the final product of this reaction sequence?
B
-OH
B
CI
SO₂H
NaCN
DMSO
. This compound does not undergo Diels-Alder reactions ber
A) it lacks electron-withdrawing groups
B) it lacks strong electron
C) It cannot al
HO-
H-OH
-H
H-OH
H-
da
C
2
in
-OH
CH₂OH
C
70% H₂SO4
reflux
HO
-H
HOH
H-OH
-H
CH₂OH
D
HO-
OH
3.
D
OH
Transcribed Image Text:13. Compound 1 is an acetyl protected precursor of the phytonutrient pterostilbene (2), a natural antioxidant founs blueberries. Which reagents would you use to synthesize 1 starting with 3 and 4? Sal A) PhB(OH)2, KCO₁ B) Pd(OAC)2, 2 PPh₁, K₂CO C) Cul, H₂O/H₂0 D) NaOEt/EtOH 14. Which is a D-sugar? O HO- HOH HO-H HO-H A CH₂OH A H A HO- --H HO-H H- HO-H 15. Which of these compounds is the best Michael acceptor? CH₂OH B 16. What is the final product of this reaction sequence? B -OH B CI SO₂H NaCN DMSO . This compound does not undergo Diels-Alder reactions ber A) it lacks electron-withdrawing groups B) it lacks strong electron C) It cannot al HO- H-OH -H H-OH H- da C 2 in -OH CH₂OH C 70% H₂SO4 reflux HO -H HOH H-OH -H CH₂OH D HO- OH 3. D OH
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