Which of the following two conformations of trans-3-methylcyclohexanol is more stable? Use the strain energy increments in the table below estimate the energy difference (a positive number) between them. 1,3-Diaxial Strain Energies for MonosubstitutedCyclohexanesSubstituentkJ/mol Substituent kJ/mol-CN, cyano|-NH20.42.95-F0.5-COOH2.95-C=CH, ethynyl 0.85-CH=CH,3.55-I0.95-CH33.64-Ci1.1-CH2CH33.65-Br1.2-CH(CH3)2 4.5-ОН1.95-C(CH3)310.5-CH56.3HOČH3 aH3Cb

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Which of the following two conformations of trans-3-methylcyclohexanol is more stable? Use the strain energy increments in the table below estimate the energy difference (a positive number) between them.

1,3-Diaxial Strain Energies for Monosubstituted
Cyclohexanes
Substituent
kJ/mol Substituent kJ/mol
-CN, cyano
|-NH2
0.4
2.95
-F
0.5
-COOH
2.95
-C=CH, ethynyl 0.85
-CH=CH,
3.55
-I
0.95
-CH3
3.64
-Ci
1.1
-CH2CH3
3.65
-Br
1.2
-CH(CH3)2 4.5
-ОН
1.95
-C(CH3)3
10.5
-CH5
6.3
HO
ČH3 a
H3C
b

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