Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and... Problem 2RQ: Is the scientific method suitable for solving problems only in the sciences? Explain. Problem 3RQ: Which of the following statements could be tested by quantitative measurement? a. Ty Cobb was a... Problem 4RQ: For each of the following pieces of glassware, provide sample measurement and discuss the number of... Problem 5RQ: A student performed an analysis of a sample for its calcium content and got the following results:... Problem 6RQ: Compare and contrast the multiplication/division significant figure rule to the significant figure... Problem 7RQ: Explain how density can be used as a conversion factor to convert the volume of an object to the... Problem 8RQ: On which temperature scale (F, C. or K) docs 1 degree represent the smallest change in temperature? Problem 9RQ: Distinguish between physical changes and chemical changes. Problem 10RQ: Why is the separation of mixtures into pure or relatively pure substances so important when... Problem 1ALQ: a. There are 365 days per year, 24 hours per day, 12 months per year, and 60 minutes per hour. Use... Problem 2ALQ Problem 3ALQ: When a marble is dropped into a beaker of water, it sinks to the bottom. Which of the following is... Problem 4ALQ Problem 5ALQ: You may have noticed that when water boils, you can see bubbles that rise to the surface of the... Problem 6ALQ: If you place a glass rod over a burning candle, the glass appears to turn black. What is happening... Problem 7ALQ: Which characteristics of a solid, a liquid, and a gas are exhibited by each of the following... Problem 8ALQ: Sketch a magnified view (showing atoms/molecules) of each of the following and explain: a. a... Problem 9ALQ: Paracelsus, a sixteenth-century alchemist and healer, adopted as his slogan: "The patients are your... Problem 10ALQ: What is wrong with the following statement? "The results of the experiment do not agree with the... Problem 11ALQ: Why is it incorrect to say that the results of a measurement were accurate but not precise? Problem 14ALQ: You have a 1.0-cm3 sample of lead and a 1.0-cm3 sample of glass. You drop each in separate beakers... Problem 15ALQ: Consider the addition of 15.4 to 28. What would a mathematician say the answer is? What would a... Problem 16ALQ: Consider multiplying 26.2 by 16.43. What would a mathematician say the answer is? What would a... Problem 17ALQ: True or false? For mathematical operation performed on two measurements, the number of significant... Problem 18ALQ: Is there a difference between a homogeneous mixture of hydrogen and oxygen in a 2:1 ratio and a... Problem 19Q: The difference between a law and a theory is the difference between what and why. Explain. Problem 20Q: The scientific method is a dynamic process. What does this mean? Problem 21Q: Explain the fundamental steps of the scientific method. Problem 22Q Problem 23Q: A measurement is a quantitative observation involving both a number and a unit. What is a... Problem 24Q: To determine the volume of a cube, a student measured one of the dimensions of the cube several... Problem 25Q: What are significant figures? Show how to indicate the number one thousand to 1 significant figure,... Problem 26Q: A cold front moves through and the temperature drops by 20 degrees. In which temperature scale would... Problem 28Q: In a multiple-step calculation, is it better to round off the numbers to the correct number of... Problem 29Q: Is the density of a gaseous substance larger or smaller than the density of a liquid or a solid at... Problem 30Q: Give four examples illustrating each of the following terms. a. homogeneous mixture b. heterogeneous... Problem 31E: Which of the following are exact numbers? a. There are 100 cm in 1 m. b. One meter equals 1.094... Problem 32E: Indicate the number of significant figures in each of the following: a. This book contains more than... Problem 33E: How many significant figures are there in each of die following values? a. 6.07 1015 b. 0.003840 c.... Problem 34E: How many significant figures are in each of the following? a. 100 b. 102 c. 103 d. 100. e. 0.0048... Problem 35E: Round off each of the following numbers to the indicated number of significant digits, and write the... Problem 36E: Use exponential notation to express the number 385,500 to a. one significant figure. b. two... Problem 37E: You have liquid in each graduated cylinder shown: You then add both samples to a beaker. How would... Problem 38E: The beakers shown below have different precisions. a. Label the amount of water in each of the three... Problem 39E: Evaluate each of the following, and write the answer to the appropriate number of significant... Problem 40E: Perform the following mathematical operations, and express each result to the correct number of... Problem 41E: Perform the following mathematical operations, and express the result to the correct number of... Problem 42E: Perform the following mathematical operations, and express the result to the correct number of... Problem 43E: Perform each of the following conversions. a. 8.43 cm to millimeters b. 2.41 102 cm to meters c.... Problem 44E: a. How many kilograms are in 1 teragram? b. How many nanometers are in 6.50 x 102 terameters? c. How... Problem 45E: Perform the following unit conversions. a. Congratulations! You and your spouse are the proud... Problem 46E: Perform the following unit conversions. a. 908 oz to kilograms b. 12.8 L to gallons c. 125 mL to... Problem 47E: Use the following exact conversion factors to perform the stated calculations: 512 yd -= 1 rod 40... 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If a sample of this copper wire has... Problem 83E: Match each description below with the following microscopic pictures. More than one picture may fit... Problem 84E: Define the following terms: solid, liquid, gas, pure substance, element, compound, homogeneous... Problem 85E: What is the difference between homogeneous and heterogeneous matter? Classify each of the following... Problem 86E: Classify the following mixtures as homogeneous or heterogeneous. a. potting soil b. white wine c.... Problem 87E: Classify each of the following as a mixture or a pure substance. a. water b. blood c. the oceans d.... Problem 88E: Suppose a teaspoon of magnesium filings and a teaspoon of powdered sulfur are placed together in a... Problem 89E: If a piece of hard, white blackboard chalk is heated strongly in a flame, the mass of the piece of... Problem 90E: During a very cold winter, the temperature may remain below freezing for extended periods. However,... 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Problem 110AE: The chemist in Example 1.14 did some further experiments. She found that the pipet used to measure... Problem 111CWP: The longest river in the world is the Nile River with a length of 4145 mi. How long is the Nile in... Problem 112CWP: Secretariat is known as the horse with the fastest run in the Kentucky Derby. If Secretariats record... Problem 113CWP: The hottest temperature recorded in the United States is 134F in Greenland Ranch, CA. The melting... Problem 114CWP Problem 115CWP: Which of the following statements is(are) true? a. A spoonful of sugar is a mixture. b. Only... Problem 116CWP: Which of the following describes a chemical property? a. The density of iron is 7.87 g/cm3. b. A... Problem 117CP: A rule of thumb in designing experiments is to avoid using a result that is the small difference... Problem 118CP: Draw a picture showing the markings (graduations) on glassware that would allow you to make each of... Problem 119CP: Many times errors are expressed in terms of percentage. The percent error is die absolute value of... Problem 120CP: A person weighed 15 pennies on a balance and recorded the following masses: 3.112 g 3.109 g 3.059 g... Problem 121CP: On October 21, 1982, the Bureau of the Mint changed the composition of pennies (see Exercise 120).... Problem 122CP: As part of a science project, you study traffic patterns in your city at an intersection in the... Problem 123CP: Sterling silver is a solid solution of silver and copper. If a piece of a sterling silver necklace... Problem 124CP: Make molecular-level (microscopic) drawings for each of the following. a. Show the differences... Problem 125CP: Confronted with the box shown in the diagram, you wish to discover something about its internal... format_list_bulleted
![General Chemistry II- Ara Sinavi
13 According to the data given below calculate k and t1/2.
For the hypothetical aqueous reaction: A B, the concentration change of A was monitored and
several derived data were tabulated and two different plots were obtained. Based on these given plots
and data:
time(min) [A] (M)
In[A]
V [A]
-0.2
0.65
-0.43
1.5
--0.4
10
0.51
-0.67
2.0
-0.6
S -0.8
20
0.42
-0.87
2.4
-1.0
30
0.36
-1.02
2.8
<-1.2-
-14
10
20
30
40
50
10
20
30
40
50
40
0.31
-1.17
3.2
time (min)
time (min)
a)
k=0.12 M1 min1 and t/2-122 min
b)
k=0.032 M1 min1 and t/2-12 min
C)
k=0.022 M1 min1 and t/2-21 min
d)
k=0.042 M1 min1 and t/2-37 min
k=0.32 M1 min' and t/2=16 min
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