105 100 95 T(°c) 90 85 80 75 70 65 60 1.2 0 1 0.8 -0.6 0.4 44 23 0.2 T-XY 0.1 0.2 20 0.3 04 0.5 0.6 0.7 0.8 09 XY 01 0 0.1 equilibrium diagram. 22 0.2 0 0.3 04 ཁ 0.5 0.6 0.7 0.8 0.9 1 *

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question

It is desired to separate a mixture of methanol and water in a flash vessel at 1 atm pressure. The equilibrium data are shown in the L-V diagram below. Using this data, answer each of the following questions.

a) The feed has 40 mol% methanol, and V/F = 30%. What are the molar fractions of the vapor and liquid, and the respective flow rates? Assume a feed of 250 kmol/h.

b) If the feed is 35 mol% methanol and it is desired to obtain a liquid product with 15 mol% methanol, what V/F ratio should be used? For a feed of 2000 lbmol/h, find the flow rates and compositions of the products.

c) The tank is operated to obtain a liquid product with 47 mol% methanol. L = 1,800 kmol/h and V/F = 0.2. What are the composition and flow rate of the feed?

d) If z = 0.4 and T = 77°C, find V/F, xA, and yA.

e) If F = 50 mol/h, z = 0.8, and yA = 0.892, find V, L, and xA.

105
100
95
T(°c)
90
85
80
75
70
65
60
1.2
0
1
0.8
-0.6
0.4
44
23
0.2
T-XY
0.1
0.2
20
0.3
04
0.5
0.6
0.7
0.8
09
XY
01
0
0.1
equilibrium diagram.
22
0.2
0
0.3
04
ཁ
0.5
0.6
0.7
0.8
0.9
1
*
Transcribed Image Text:105 100 95 T(°c) 90 85 80 75 70 65 60 1.2 0 1 0.8 -0.6 0.4 44 23 0.2 T-XY 0.1 0.2 20 0.3 04 0.5 0.6 0.7 0.8 09 XY 01 0 0.1 equilibrium diagram. 22 0.2 0 0.3 04 ཁ 0.5 0.6 0.7 0.8 0.9 1 *
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