1.03 13)2S 19 18 17 6 15 H₂ Pd or Pt (catalyst) HBr 20 12 3 9 HBr ROOR (peroxide) O H H₂SO HC 1. ВН 2. H2

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
A
8.8
О А
B
D
""Br
Br₂
CH3OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
1. Os04
2. H₂O₂
B
1.03
2. (CH3)2S
17
16
78
Br
"Br
15
CH₂CO3H
(peroxyacid)
14
19
MCPBA
H₂2
Pd or Pt (catalyst)
HBr
20 1
2. H₂O*
Pd or Ni (catalyst)
2
D₂ (deuterium)
с
3
FtOH
Br
BH3 THF
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
H₂O
1. BH3 THF
2. H₂O₂, NaOH
Bra
Br₂
H₂O
D
a a
"Br
Br
aa
Br
"Br
Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn-vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. A 8.8 О А B D ""Br Br₂ CH3OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ B 1.03 2. (CH3)2S 17 16 78 Br "Br 15 CH₂CO3H (peroxyacid) 14 19 MCPBA H₂2 Pd or Pt (catalyst) HBr 20 1 2. H₂O* Pd or Ni (catalyst) 2 D₂ (deuterium) с 3 FtOH Br BH3 THF HBr ROOR (peroxide) H₂O H₂SO4 HCI H₂O 1. BH3 THF 2. H₂O₂, NaOH Bra Br₂ H₂O D a a "Br Br aa Br "Br
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