1.000-g sample containing  bromide was dissolved in sufficient water to give 100.0 mL.  A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 11.70 mL of 0.002146 M EDTA The other 50.00 mL remaining solution was also analyzed for its  Br- content by potentiometry using a metallic electrode of the second kind. Ecell recorded in running the solution using the potentiometric set-up was Ecell = 0.0286 V.       (E0Ag/AgBr = 0.095 V) g)  Compute for Eind.    h) Compute  pBr  in the 50.00 mL aliquot.   i)  Compute for % NaBr ( in the potentiometric  technique).

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A 1.000-g sample containing  bromide was dissolved in sufficient water to give 100.0 mL.  A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II):

Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br-

The liberated nickel ion required 11.70 mL of 0.002146 M EDTA

The other 50.00 mL remaining solution was also analyzed for its  Br- content by potentiometry using a metallic electrode of the second kind.

Ecell recorded in running the solution using the potentiometric set-up was Ecell = 0.0286 V.       (E0Ag/AgBr = 0.095 V)

g)  Compute for Eind.   

h) Compute  pBr  in the 50.00 mL aliquot.  

i)  Compute for % NaBr ( in the potentiometric  technique). 

j) Calculate the error between the obtained % NaBr fr the EDTA titration technique and the % NaBr from the potentiometric technique. 

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