None 1. Write the Slater determinant and the Hartree-Fock equation for the ground state ofhelium atom. Evaluate the Hartree-Fock potentials using u₁s =2. Write the 25+¹LJ ground states for Al, Mn and Br.(Aear + Be-Br).3. Calculate the possible spectral terms assuming L-S and j-j coupling for nd² electronicconfiguration.

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Answered: 1. Write the Slater determinant and the…

1. Write the Slater determinant and the Hartree-Fock equation for the ground state of helium atom. Evaluate the Hartree-Fock potentials using u₁s = (Aear + Be-Br). 1

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter12: Atoms And Molecules

Section: Chapter Questions

Problem 12.22E: Write a Slater determinant for the lithide ion, Li.

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1. Write the Slater determinant and the Hartree-Fock equation for the ground state of
helium atom. Evaluate the Hartree-Fock potentials using u₁s =
2. Write the 25+¹LJ ground states for Al, Mn and Br.
(Aear + Be-Br).
3. Calculate the possible spectral terms assuming L-S and j-j coupling for nd² electronic
configuration.

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