1. Which of the following metal hydrides should be the most acidic? Clearly explain your reasoning. a) HNb(CO)6 -or- HV(CO)s(PMe3) b) HRh(CO)(PPh3)2 HRh(CO)2[P(OPh)3] -or- c) [HOs(PM@3)(dmpe)2]* HRe(CF3)2(CO)2[P(OME3)3]2 -or-

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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1. Which of the following metal hydrides should be the most acidic? Clearly explain
your reasoning.
a) HNb(CO)6
HV(CO)s(PMe3)
-or-
b) HRh(CO)(PPh3)2
HRh(CO)2[P(OPh)3]
-or-
c) [HOs(PME3)(dmpe)2]* -or-
HRe(CF3)2(CO)2[P(OMe3)3]2
d) [HC0C1(NH3)4]*
-or-
СpFe(H/фрре)
Transcribed Image Text:1. Which of the following metal hydrides should be the most acidic? Clearly explain your reasoning. a) HNb(CO)6 HV(CO)s(PMe3) -or- b) HRh(CO)(PPh3)2 HRh(CO)2[P(OPh)3] -or- c) [HOs(PME3)(dmpe)2]* -or- HRe(CF3)2(CO)2[P(OMe3)3]2 d) [HC0C1(NH3)4]* -or- СpFe(H/фрре)
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