1). Which d-orbitals become t, orbitals according to the character table below? Character table for Ta point group Esc, c, 6s, linear, quadratie rotations TOO I R, R. R K. y. ) a. d and d. b. dand d, c. dand d d. d, and d. 2). Which one of the following reactions is incorrect? a. [PtBr.) + 2PR, à trans-[PtBr,(PR,)) + 2Br b. [Pt(NH,)Br] + NH, àcis-[Pt(NH,),Br.] + Br c. [Pt(CH,=CH,)CIJ + NH, àtrans-[Pt(CH,=CH,)(NH,)CIJ + CI d. [Pt(PR,).J" + 2CI à trans-[PICI,(PR,)) + 2PR, 3). What is the crystal field stabilization energy of (Ir(bpy).]^? . а. О b. -2.4Ao + 3P C. -2.4Ao + 2P d. -0.4Ao + P 4). What is the crystal field stabilization energy of (Mn(H,O).}^? (H,O is a weak field ligand) а. 0 b. 2Δο + 2P C. -Ao + 2P d. -Ao +P

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Chapter1: Chemical Foundations
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1). Which d-orbitals become t, orbitals according to the character
table below?
Character table for Ta point group
Esc, c, 6s,
linear,
quadratie
rotations
TOO I R, R. R
K. y. )
a. d and d.
b. dand d,
c. dand d
d. d, and d.
2). Which one of the following reactions is incorrect?
a. [PtBr.) + 2PR, à trans-[PtBr,(PR,)) + 2Br
b. [Pt(NH,)Br] + NH, àcis-[Pt(NH,),Br.] + Br
c. [Pt(CH,=CH,)CIJ + NH, àtrans-[Pt(CH,=CH,)(NH,)CIJ + CI
d. [Pt(PR,).J" + 2CI à trans-[PICI,(PR,)) + 2PR,
3). What is the crystal field stabilization energy of (Ir(bpy).]^? .
а. О
b. -2.4Ao + 3P
C. -2.4Ao + 2P
d. -0.4Ao + P
4). What is the crystal field stabilization energy of (Mn(H,O).}^? (H,O
is a weak field ligand)
а. 0
b. 2Δο + 2P
C. -Ao + 2P
d. -Ao +P
Transcribed Image Text:1). Which d-orbitals become t, orbitals according to the character table below? Character table for Ta point group Esc, c, 6s, linear, quadratie rotations TOO I R, R. R K. y. ) a. d and d. b. dand d, c. dand d d. d, and d. 2). Which one of the following reactions is incorrect? a. [PtBr.) + 2PR, à trans-[PtBr,(PR,)) + 2Br b. [Pt(NH,)Br] + NH, àcis-[Pt(NH,),Br.] + Br c. [Pt(CH,=CH,)CIJ + NH, àtrans-[Pt(CH,=CH,)(NH,)CIJ + CI d. [Pt(PR,).J" + 2CI à trans-[PICI,(PR,)) + 2PR, 3). What is the crystal field stabilization energy of (Ir(bpy).]^? . а. О b. -2.4Ao + 3P C. -2.4Ao + 2P d. -0.4Ao + P 4). What is the crystal field stabilization energy of (Mn(H,O).}^? (H,O is a weak field ligand) а. 0 b. 2Δο + 2P C. -Ao + 2P d. -Ao +P
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