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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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
Transcribed Image Text:1. Use the thermodynamic values in the table below to determine enthalpy, entropy, and free
energy for the copper/zinc cell reaction in Experiment I (b).
Species
AH", (kJ/mol)
S (J/mol-K)
Cu (s)
33
Cu" (aq)
64.9
-98
Zn (s)
42
Zn* (aq)
- 153.4
- 109
Report your calculated value with accurate units and significant figures for each of the following
thermodynamic values using the above table:
AS"pn =
AH°an =
AG°rxn =
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- Nonearrow_forward3. Magnesium binds ATP: non ideal a) The value of AG is -36 kJ/mol at 25 °C. If a solution is at standard conditions, what is the concentration of Mg"? 46=A6% +RTIN (GR =-36000J/mol + (8.310/1.1) (24P) In ( ) ( ) =-38477.57 kJ/mol (5) b) Magnesium is commonly found throughout cells át a constant concentration of about 25 mM. You can define a new standard state called the biological magnesium standard state. The value of AG at the magnesium standard state can be denoted AGN Explain how you can transform the equations: 4G₁ = 46axy +RTING and AGREN AGEN+RTINQ' HAHA+RTIN Into the equations: + M₂² Mg PA HA +RTIN aA-A-CA MAMA+RT In CGA) 25 298k A Gixn = -36000 J/molke standard = | gª VA-MAMS +RTIO ams This equation is for monideal soutions derning from Icheal gas law- Usea withiens and AGRXN = AGN + RTINQ AGAG" +RTIN (G) AGA AG" + RT INQ Aben AGn + RTING A Gren AGM +RTINGING c) If you define the value of ae" as exactly 25 mM, what is the value of AGN? 25mM= 0.025M 46+xn = Elral), Rrink =…arrow_forward-26.93 is the answer I keep getting but says it is incorrectarrow_forward
- Consider the reaction 2H202(1)2H20(1) + 02(g) Using the standard thermodynamic data in the tables linked above, calculate the equilibrium constant for this reaction at 298.15K. ANSWER: Submit Answer Retry Entire Group 9 more group attempts remainingarrow_forwardThe table below provides data for the enthalpy and entropy of formation of compounds A and B at standard conditions (298 K) Compound DHfo (kJ mol-1) Sfo(J K-1mol-1) A –135.2 189.2 B –157.6 192.1 (b) A reversible isomerization reaction converts reactant A to product X. Calculate the Gibbs energy change at non-standard conditions (310 K) if the concentration of A is 2 x 10-4M and that of X is 3 x 10-6 M. Comment on whether the reaction is spontaneous at these conditions. The equilibrium constant Keq = 0.05. Assume standard temperature is 298K.arrow_forward18.3 Gibbs Free E... 21,099 = 5.3 Enthalpies of... O ELECTROCHEMISTRY Ranking the strength of oxidizing and reducing agents using... species Br₂ (1) Mg²+ (aq) Na (aq) Ag (aq) Use the information in the ALEKS Data tab to sort the following chemical species by oxidizing power. Explanation oxidizing power choose one v X 18.5 Gibbs Free E... choose one v choose one choose one Check 5 S . Reading Schedule 19.6 Reduction Po... Ⓒ tv Search or type URL 2022 McGraw Hill LLC Aarrow_forward
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