1. Synthesis of Aldehydes: A. B. C. Oxidation of 1° alcohol to an aldehyde Reagents: (i) Pyridinium chlorochromate (PCC)- Shop et ex epidehode Reagents: (ii) Dess-Martin Periodinane; CH₂Cl₂ Ozonolysis of Alkenes to aldehydes/ketones Reagents: 03; then Zn, H3O+

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1. Synthesis of Aldehydes:
8
B.
C.
& Ketones Synthesis
A. Oxidation of 1° alcohol to an aldehyde
D
PA
Reagents: (i) Pyridinium chlorochromate (PCC)-> top
Reagents: (ii) Dess-Martin Periodinane; CH₂Cl₂
B.
C.
Ozonolysis of Alkenes to aldehydes/ketones
Reagents: 03; then Zn, H3O+
II. Synthesis of Ketones
A. Oxidation of 2° alcohol to a ketone
Reagents: Jones Reagent (CrO3 in aquous H₂SO4; acetone)
Reagents: Pyridinium chlorochromate (PCC)
Reagents: Dess-Martin Periodinane: CH₂Cl₂
Reagents: K₂Cr₂O7 in aquous H₂SO4
pidehode
Red
M
Partial Reduction of Esters to an aldehyde
Relagents: Diisobutyl aluminum hydride (DIBAH) in toluene, -78 °C, then
H3O+
Reduction of Acid chloride to an aldehyde (Rosenmund Reduction)
Reagents H₂, Pd, BaSO4
D.
E. Reagnets: KMnO4, heat
F.
Reagents: Ozonolysis of Alkenes to aldehydes/ketones
G. Reagents: Oxymercuration of terminal and internal alkynes; HgSO4,
H₂SO4, H2₂O
H. Reagents: Friedel-Crafts Acylation (Electrohilic Aromatic Substitution);
RC(O)CI, AICI 3
Transcribed Image Text:1. Synthesis of Aldehydes: 8 B. C. & Ketones Synthesis A. Oxidation of 1° alcohol to an aldehyde D PA Reagents: (i) Pyridinium chlorochromate (PCC)-> top Reagents: (ii) Dess-Martin Periodinane; CH₂Cl₂ B. C. Ozonolysis of Alkenes to aldehydes/ketones Reagents: 03; then Zn, H3O+ II. Synthesis of Ketones A. Oxidation of 2° alcohol to a ketone Reagents: Jones Reagent (CrO3 in aquous H₂SO4; acetone) Reagents: Pyridinium chlorochromate (PCC) Reagents: Dess-Martin Periodinane: CH₂Cl₂ Reagents: K₂Cr₂O7 in aquous H₂SO4 pidehode Red M Partial Reduction of Esters to an aldehyde Relagents: Diisobutyl aluminum hydride (DIBAH) in toluene, -78 °C, then H3O+ Reduction of Acid chloride to an aldehyde (Rosenmund Reduction) Reagents H₂, Pd, BaSO4 D. E. Reagnets: KMnO4, heat F. Reagents: Ozonolysis of Alkenes to aldehydes/ketones G. Reagents: Oxymercuration of terminal and internal alkynes; HgSO4, H₂SO4, H2₂O H. Reagents: Friedel-Crafts Acylation (Electrohilic Aromatic Substitution); RC(O)CI, AICI 3
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