1. O3 PRODUK/ PRODUK/ + 2. Mezs PRODUCT C PRODUCT D

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter1: Introduction
Section: Chapter Questions
Problem 1.4QAP
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Question

The reaction of Compound B with O3, followed by Me2S gave two products, C and D (Scheme 1).

The mass spectrums of products C and D are shown below.

Identify the structures of products C and D. Provide explanation for your answer (based on mass spectrometry interpretation).

1. O3
PRODUK/
PRODUK/
PRODUCT C
PRODUCT D
2. Me2s
B
Transcribed Image Text:1. O3 PRODUK/ PRODUK/ PRODUCT C PRODUCT D 2. Me2s B
100
| 43
SPEKTRUM
HASIL CI
SPECTRUM FOR
80
PRODUCT C
40
20
[M]*
m/z 86
58
71
10
20
30
40
50
60
70
80
90
100
m/z
100
44
MS-NU-3536
SPEKTRUM HASIL DI
SPECTRUM FOR
PRODUCT D
80
29
40
20
[M]*
m/z 86
85
25
50
75
100
125
150
m/z
Relative Intensity
Relative Intensity
Transcribed Image Text:100 | 43 SPEKTRUM HASIL CI SPECTRUM FOR 80 PRODUCT C 40 20 [M]* m/z 86 58 71 10 20 30 40 50 60 70 80 90 100 m/z 100 44 MS-NU-3536 SPEKTRUM HASIL DI SPECTRUM FOR PRODUCT D 80 29 40 20 [M]* m/z 86 85 25 50 75 100 125 150 m/z Relative Intensity Relative Intensity
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