1. For each of the following redox reactions: i. Write the oxidation half reaction ii. Write the reduction half reaction ii. Determine the Ecell at 25°C iv. Using the Eceu determine the Free Gibbs Energy in kJ/mol V. Based on the Ecelu and Free Gibbs Energy determine whether the reaction is spontaneous or nonspontaneous. a. 2F23*(aq) + I'(aq) → 2FE2*(aq) + I2(s) b. Cr20,2(aq) + 6Fe2*(aq) + 14H*(aq) → 2Cr³*(aq) + 6FE3*(aq) + 7H2O(1)

74. A voltaic cell employs the redox reaction: Sn²+(aq) + Pb(s) Sn(s) + Pb2+(aq) E° cell = 0.010 V Calculate the cell potential, Ecell, at 25°C under each set of conditions. a. [Pb2+] = 0.010 M; [Sn²+] = 0.010 M b. [Pb2+] c. [Pb2+] = = 1.0 × 10 6 M; [Sn²+] = 2.0 M 1.5 M; [Sn2] = 0.010 M

17. Which reaction will not occur as suggested? Al (s) + SnCh(aq)AIC13(aq) + Sn(s) b. H2(g)+ AGNO3(aq) → HNO3(aq) + Ag(s) Mg(s) + CUSO4(aq) Cu(s) + MgSO4(aq) d. Mg(s)+ CaSO4(aq)MgSO4(aq) + Ca(s) Ba (s) + HCl(aq) BaCl2(aq) + H2(g) а. с. -> -> e. ->

11. What is AG° for the reaction driving the following voltaic cell? Co (s) | Co²+ (aq) || Mn³+ (aq), Mn²+ (aq) | Pt (s) A. -175 kJ +175 kJ B. -351 kJ +351 kJ C. -527 kJ D. E.

Calculate the standard reaction free energy (AGº) for the following unbalanced redox reaction in acidic conditions. (HINT: You need to balance) NO(g) + Cu²+ (aq) → HNO₂(aq) + Cu+ (aq) The potential for the oxidation of NO (g) to HNO₂ (aq) is -0.983 V. The potential for the reduction of Cu²+ (aq) to Cu* (aq) is 0.153 V. The standard cell potential (Eºcell) for the reaction above is [Select ] V. There are [Select] The standard reaction free energy (AGO) for this redox reaction is [Select] kJ. This redox reaction [Select] at 25°C. of electrons transferred during this reaction.

11. Consider the following reaction and its AG-AG• at 25.00 °C. 12 Coeside 2Ag*(aq)+Cu(s) 2Ag(s)+Cu*(aq) AG =-88660 J/mol a. Calculate the standard cell potential, Ecellº, for the reaction. b. Calculate the equilibrium constant, K, for the reaction. Wtoxided what is reduced? CLEAREY

Calculate the K and AG for the following reaction at 25 °C: Mg(s) + Pb2+(aq)=Mg2+(aq) + Pb (s) Note: Reference the Standard reduction potentials at 25 °C and Fundamental constants tables for additional information. Part 1 of 2 Round your answer to 3 significant digits. Кс Part 2 of 2 G Round your answer to 4 significant digits. AG° kJ mol

Determine if the reaction below is spontaneous.Cl2(g) + 2 F–(aq) ⇌ F2(g) + 2 Cl–(aq)a. Based on the given reaction, write the reduction half-reaction.b. Based on the given reaction, write the oxidation half-reaction.c. By looking at the reduction potential table below, calculate the standard cell potential.

The standard EMF for the cell using the overall cell reaction below is +0.84 V: 2Al(s) + 312 (s) 2A1³+ (aq) + 61 (aq) What is AGO for the cell reaction in kJ? Express your answer in decimal notation to one decimal place, without units.

H11. Consider the voltaic cell H+ (aq, ?? M) H₂(g, 1 atm)||Cu(s) Cu²+ (aq. 0.1 M). Ecell for this cell at 25 C was +0.360V. What was the pH of the anode solution? A. 0 ABCDE B. C. D. E. 0.89 3.2 7.0 11.7