1. Estimate AH° for each of the following conformational equilibria: (a) CH3 CH3 H CH3 H3C. ✓ CH3 H H H H CH3 H (b) H CH3 H3C. CH3 H3C CH3 H3C CH3 H3C H H H (c) ૭ CH3 -CH3 CH3 -CH3

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter19: Carboxylic Anhydrides, Esters, And Amides
Section: Chapter Questions
Problem 19.47P
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1. Estimate AH° for each of the following conformational equilibria:
(a)
CH3
CH3
H.
CH3
H3C
CH3
H
H
H
H
CH3
H
(b)
H
CH3
H3C
CH3
H3C CH3
H3C
CH3
H3C
H
H
H
(c)
CH3
0
-CH3
CH3
-CH3
Transcribed Image Text:1. Estimate AH° for each of the following conformational equilibria: (a) CH3 CH3 H. CH3 H3C CH3 H H H H CH3 H (b) H CH3 H3C CH3 H3C CH3 H3C CH3 H3C H H H (c) CH3 0 -CH3 CH3 -CH3
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